Two-dimensional supramolecular nanopatterns formed by the coadsorption of guanine and uracil at the liquid/solid interface

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  • Department of Physics and Astronomy
  • Interdisciplinary Nanoscience Center
A novel supramolecular nanostructure formed by the coadsorption of the complementary nucleobases guanine (G) and uracil (U) at the liquid (1-octanol solvent)/solid (graphite) interface is revealed by scanning tunneling microscopy (STM). The GU supramolecular structure is distinctly different from the structures observed by STM when the individual nucleobases (NB) are adsorbed on graphite in the control experiments. Using a systematic methodology and ab initio density functional theory (DFT), an atomistic structural model is proposed for the supramolecular coadsorbed GU structure, which consists of a periodic repetition of cyclic units based on the strongest GU base pairing.
Original languageEnglish
JournalJournal of the American Chemical Society
Volume130
Issue2
Pages (from-to)695-702
Number of pages7
ISSN0002-7863
DOIs
Publication statusPublished - 2007

    Research areas

  • Adsorption, Graphite, Guanine, Microscopy, Scanning Tunneling, Nanostructures, Octanols, Uracil

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