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Two-dimensional sandwich-type, graphene-based conjugated microporous polymers

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaperJournal articleResearchpeer-review

  • Xiaodong Zhuang
  • ,
  • Fan Zhang
  • ,
  • Dongqing Wu
  • ,
  • Nina Forler
  • ,
  • Haiwei Liang
  • ,
  • Manfred Wagner
  • ,
  • Dominik Gehrig
  • ,
  • Michael Ryan Hansen, Denmark
  • Frédéric Laquai
  • ,
  • Xinliang Feng
Better than sliced bread: Layered two-dimensional graphene-based conjugated microporous polymers, which exhibit high surface areas and fluorescence quenching, can be prepared by a graphene-mediated Sonogashira-Hagihara coupling. Upon thermal pyrolysis, these porous polymers are readily converted into porous carbon materials with intriguing physical and electrochemical properties (see scheme; pink spheres=thiophene, thiazole, or pyridine units).
Original languageEnglish
JournalAngewandte Chemie International Edition
Volume52
Issue37
Pages (from-to)9668-72
Number of pages5
ISSN1433-7851
DOIs
Publication statusPublished - 9 Sep 2013

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