Abstract
Better than sliced bread: Layered two-dimensional graphene-based conjugated microporous polymers, which exhibit high surface areas and fluorescence quenching, can be prepared by a graphene-mediated Sonogashira-Hagihara coupling. Upon thermal pyrolysis, these porous polymers are readily converted into porous carbon materials with intriguing physical and electrochemical properties (see scheme; pink spheres=thiophene, thiazole, or pyridine units).
Original language | English |
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Journal | Angewandte Chemie International Edition |
Volume | 52 |
Issue | 37 |
Pages (from-to) | 9668-72 |
Number of pages | 5 |
ISSN | 1433-7851 |
DOIs | |
Publication status | Published - 9 Sept 2013 |