Three pulse recoupling and phase jump matching

James Lin, R.G. Griffin, Niels Christian Nielsen, Navin Khaneja

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaperJournal articleResearchpeer-review

Abstract

The paper describes a family of novel recoupling pulse sequences, called three pulse recoupling. These pulse sequences can be employed for both homonuclear and heteronuclear recoupling experiments and are robust to dispersion in chemical shifts and rf-inhomogeneity. These recoupling pulse sequences can be used in design of two-dimensional solid state NMR experiments that use powdered dephased antiphase coherence (γ preparation) to encode chemical shifts in the indirect dimension. Both components of this chemical shift encoded gamma-prepared states can be refocused into inphase coherence by a recoupling element. This helps to achieve sensitivity enhancement in 2D NMR experiments by quadrature detection.

Original languageEnglish
JournalJournal of Magnetic Resonance
Volume263
Pages (from-to)172-183
Number of pages12
ISSN1090-7807
DOIs
Publication statusPublished - Feb 2016

Keywords

  • Gamma preparation
  • Hartmann-Hahn matching
  • MAS
  • Quadrature detection
  • Recoupling

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