The missing link between zeolites and polyoxometalates

Guangmei Wang; Katharina V. Dorn; Stefanie Siebeneichler; Martin Valldor; Volodymyr Smetana; Anja Verena Mudring

doi:10.1126/sciadv.add9320

The missing link between zeolites and polyoxometalates

Guangmei Wang, Katharina V. Dorn, Stefanie Siebeneichler, Martin Valldor, Volodymyr Smetana, Anja Verena Mudring^*

^*Corresponding author for this work

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

2 Citations (Scopus)

Abstract

Open framework materials such as zeolites and metalorganic frameworks are garnering tremendous interest because of their intriguing architecture and attractive functionalities. Thus, new types of open framework materials are highly sought after. Here, we present the discovery of completely new inorganic framework materials, where, in contrast to conventional inorganic open frameworks, the scaffold is not based on tetrahedral EO4 (E = main group element) but octahedral MO6 (M = transition metal) building blocks. These structural features place them closer to polyoxometalates than zeolites. The first representatives of this class of materials are [(R)24(NH4)14(PO(OH)2)6]·[M134(PO3(OH,F))96F120] (M = Co, R = C2Py = 1-ethylpyridinium and M = Ni, R = C4C1Py = 1-butyl-3-methylpyridinium) featuring interlinked fullerene-like nanosphere cavities. Having a transition metal building up the framework brings about interesting properties, for example, spin-glass behavior, and, with this particular topology, a hedgehog-like spin orientation.

Original language	English
Article number	eadd9320
Journal	Science Advances
Volume	8
Issue	46
Number of pages	6
ISSN	2375-2548
DOIs	https://doi.org/10.1126/sciadv.add9320 https://doi.org/10.1126/sciadv.add9320
Publication status	Published - Nov 2022

Access to Document

10.1126/sciadv.add9320Licence: CC BY-NC
10.1126/sciadv.add9320

Cite this

@article{e2cf1ce9905e4f90a38451fac3cf40be,

title = "The missing link between zeolites and polyoxometalates",

abstract = "Open framework materials such as zeolites and metalorganic frameworks are garnering tremendous interest because of their intriguing architecture and attractive functionalities. Thus, new types of open framework materials are highly sought after. Here, we present the discovery of completely new inorganic framework materials, where, in contrast to conventional inorganic open frameworks, the scaffold is not based on tetrahedral EO4 (E = main group element) but octahedral MO6 (M = transition metal) building blocks. These structural features place them closer to polyoxometalates than zeolites. The first representatives of this class of materials are [(R)24(NH4)14(PO(OH)2)6]·[M134(PO3(OH,F))96F120] (M = Co, R = C2Py = 1-ethylpyridinium and M = Ni, R = C4C1Py = 1-butyl-3-methylpyridinium) featuring interlinked fullerene-like nanosphere cavities. Having a transition metal building up the framework brings about interesting properties, for example, spin-glass behavior, and, with this particular topology, a hedgehog-like spin orientation.",

author = "Guangmei Wang and Dorn, {Katharina V.} and Stefanie Siebeneichler and Martin Valldor and Volodymyr Smetana and Mudring, {Anja Verena}",

year = "2022",

month = nov,

doi = "10.1126/sciadv.add9320",

language = "English",

volume = "8",

journal = "Science Advances",

issn = "2375-2548",

publisher = "American Association for the Advancement of Science",

number = "46",

}

TY - JOUR

T1 - The missing link between zeolites and polyoxometalates

AU - Wang, Guangmei

AU - Dorn, Katharina V.

AU - Siebeneichler, Stefanie

AU - Valldor, Martin

AU - Smetana, Volodymyr

AU - Mudring, Anja Verena

PY - 2022/11

Y1 - 2022/11

N2 - Open framework materials such as zeolites and metalorganic frameworks are garnering tremendous interest because of their intriguing architecture and attractive functionalities. Thus, new types of open framework materials are highly sought after. Here, we present the discovery of completely new inorganic framework materials, where, in contrast to conventional inorganic open frameworks, the scaffold is not based on tetrahedral EO4 (E = main group element) but octahedral MO6 (M = transition metal) building blocks. These structural features place them closer to polyoxometalates than zeolites. The first representatives of this class of materials are [(R)24(NH4)14(PO(OH)2)6]·[M134(PO3(OH,F))96F120] (M = Co, R = C2Py = 1-ethylpyridinium and M = Ni, R = C4C1Py = 1-butyl-3-methylpyridinium) featuring interlinked fullerene-like nanosphere cavities. Having a transition metal building up the framework brings about interesting properties, for example, spin-glass behavior, and, with this particular topology, a hedgehog-like spin orientation.

AB - Open framework materials such as zeolites and metalorganic frameworks are garnering tremendous interest because of their intriguing architecture and attractive functionalities. Thus, new types of open framework materials are highly sought after. Here, we present the discovery of completely new inorganic framework materials, where, in contrast to conventional inorganic open frameworks, the scaffold is not based on tetrahedral EO4 (E = main group element) but octahedral MO6 (M = transition metal) building blocks. These structural features place them closer to polyoxometalates than zeolites. The first representatives of this class of materials are [(R)24(NH4)14(PO(OH)2)6]·[M134(PO3(OH,F))96F120] (M = Co, R = C2Py = 1-ethylpyridinium and M = Ni, R = C4C1Py = 1-butyl-3-methylpyridinium) featuring interlinked fullerene-like nanosphere cavities. Having a transition metal building up the framework brings about interesting properties, for example, spin-glass behavior, and, with this particular topology, a hedgehog-like spin orientation.

UR - http://www.scopus.com/inward/record.url?scp=85142201571&partnerID=8YFLogxK

U2 - 10.1126/sciadv.add9320

DO - 10.1126/sciadv.add9320

M3 - Journal article

C2 - 36383662

AN - SCOPUS:85142201571

SN - 2375-2548

VL - 8

JO - Science Advances

JF - Science Advances

IS - 46

M1 - eadd9320

ER -

The missing link between zeolites and polyoxometalates

Abstract

Access to Document

Other files and links

Fingerprint

Cite this