Spin density measurement of water-bridged Co-dimer using polarized neutrons

Research output: Contribution to conferencePosterResearch

  • Emil Damgaard-Møller
  • Jacob Overgaard
  • Nick Chilton, School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL
  • ,
  • James Walsh, University of Manchester
  • ,
  • Anne Stunault, Institut Laue-Langevin, Grenoble, France
  • Oscar Fabelo, Institut Laue-Langevin, Grenoble, France
  • Venkatesha Rama Hathwar, University of Tsukuba
  • ,
  • Maja Thomsen
The nature of magnetic super-exchange through M-O-M bonds for spin-only metal ions is nowadays fairly well understood, but for ions with first order orbital momentum, the theory is much more complicated, and the nature of the coupling between the two spin centers is harder to evaluate. I here present an experimentally determined spin density using polarized neutron diffraction in a simple water-bridged cobalt dimer [Co2(H2O)(piv)4(Hpiv)2(py)2] which is known to have a small ferromagnetic coupling between the spin centers. Visualizing the SDD could get us one step further in understanding the coupling pathways between ions with first order orbital momentum
Original languageEnglish
Publication year2 Jun 2017
Publication statusPublished - 2 Jun 2017
EventDanscatt 2017 - Odense, Denmark
Duration: 1 Jun 20172 Jun 2017

Conference

ConferenceDanscatt 2017
CountryDenmark
CityOdense
Period01/06/201702/06/2017

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