Solid-state 87Rb NMR of RbVO3. A comparison of experiments for retrieving chemical shielding and quadrupole coupling tensorial interactions

Thomas Vosegaard; Jørgen Skibsted; Henrik Bildsøe; Hans J. Jakobsen

doi:10.1016/S0926-2040(99)00021-1

Solid-state ⁸⁷Rb NMR of RbVO₃. A comparison of experiments for retrieving chemical shielding and quadrupole coupling tensorial interactions

Thomas Vosegaard, Jørgen Skibsted, Henrik Bildsøe, Hans J. Jakobsen^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

9 Citations (Scopus)

Abstract

Solid-state ⁸⁷Rb NMR spectra for a powder and single crystal of RbVO₃ have been acquired for the central transition at two magnetic field strengths (9.4 and 14.1 T) and using two single-crystal NMR probes of different design. The powder spectra have been obtained using spin-echo techniques without sample spinning because the widths of the spectra are in the range 100-150 kHz. The spectra are analyzed in terms of the chemical shielding and quadrupole coupling interactions and the parameters are compared in an evaluation of the precision for the techniques. Parameters of high precision including the relative orientation for the two tensors are obtained from the single-crystal spectra at 14.1 T. Finally, the orientations of the two tensors in the crystal frame are deduced from the crystal symmetry and an XRD analysis.

Original language	English
Journal	Solid State Nuclear Magnetic Resonance
Volume	14
Issue	3-4
Pages (from-to)	203-210
Number of pages	8
ISSN	0926-2040
DOIs	https://doi.org/10.1016/S0926-2040(99)00021-1
Publication status	Published - 1999

Keywords

Rb single-crystal NMR
Rb static-powder NMR
Chemical shielding anisotropy
Quadrupole coupling
RbVO

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10.1016/S0926-2040(99)00021-1

http://www.scopus.com/inward/record.url?scp=0033181338&partnerID=8YFLogxK

Cite this

@article{aff52475475f4a31b2ab48351187cb79,

title = "Solid-state 87Rb NMR of RbVO3. A comparison of experiments for retrieving chemical shielding and quadrupole coupling tensorial interactions",

abstract = "Solid-state 87Rb NMR spectra for a powder and single crystal of RbVO3 have been acquired for the central transition at two magnetic field strengths (9.4 and 14.1 T) and using two single-crystal NMR probes of different design. The powder spectra have been obtained using spin-echo techniques without sample spinning because the widths of the spectra are in the range 100-150 kHz. The spectra are analyzed in terms of the chemical shielding and quadrupole coupling interactions and the parameters are compared in an evaluation of the precision for the techniques. Parameters of high precision including the relative orientation for the two tensors are obtained from the single-crystal spectra at 14.1 T. Finally, the orientations of the two tensors in the crystal frame are deduced from the crystal symmetry and an XRD analysis.",

keywords = "Rb single-crystal NMR, Rb static-powder NMR, Chemical shielding anisotropy, Quadrupole coupling, RbVO",

author = "Thomas Vosegaard and J{\o}rgen Skibsted and Henrik Bilds{\o}e and Jakobsen, {Hans J.}",

year = "1999",

doi = "10.1016/S0926-2040(99)00021-1",

language = "English",

volume = "14",

pages = "203--210",

journal = "Solid State Nuclear Magnetic Resonance",

issn = "0926-2040",

publisher = "Elsevier B.V.",

number = "3-4",

}

Solid-state ⁸⁷Rb NMR of RbVO₃. A comparison of experiments for retrieving chemical shielding and quadrupole coupling tensorial interactions. / Vosegaard, Thomas ; Skibsted, Jørgen; Bildsøe, Henrik et al.
In: Solid State Nuclear Magnetic Resonance, Vol. 14, No. 3-4, 1999, p. 203-210.

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

TY - JOUR

T1 - Solid-state 87Rb NMR of RbVO3. A comparison of experiments for retrieving chemical shielding and quadrupole coupling tensorial interactions

AU - Vosegaard, Thomas

AU - Skibsted, Jørgen

AU - Bildsøe, Henrik

AU - Jakobsen, Hans J.

PY - 1999

Y1 - 1999

N2 - Solid-state 87Rb NMR spectra for a powder and single crystal of RbVO3 have been acquired for the central transition at two magnetic field strengths (9.4 and 14.1 T) and using two single-crystal NMR probes of different design. The powder spectra have been obtained using spin-echo techniques without sample spinning because the widths of the spectra are in the range 100-150 kHz. The spectra are analyzed in terms of the chemical shielding and quadrupole coupling interactions and the parameters are compared in an evaluation of the precision for the techniques. Parameters of high precision including the relative orientation for the two tensors are obtained from the single-crystal spectra at 14.1 T. Finally, the orientations of the two tensors in the crystal frame are deduced from the crystal symmetry and an XRD analysis.

AB - Solid-state 87Rb NMR spectra for a powder and single crystal of RbVO3 have been acquired for the central transition at two magnetic field strengths (9.4 and 14.1 T) and using two single-crystal NMR probes of different design. The powder spectra have been obtained using spin-echo techniques without sample spinning because the widths of the spectra are in the range 100-150 kHz. The spectra are analyzed in terms of the chemical shielding and quadrupole coupling interactions and the parameters are compared in an evaluation of the precision for the techniques. Parameters of high precision including the relative orientation for the two tensors are obtained from the single-crystal spectra at 14.1 T. Finally, the orientations of the two tensors in the crystal frame are deduced from the crystal symmetry and an XRD analysis.

KW - Rb single-crystal NMR

KW - Rb static-powder NMR

KW - Chemical shielding anisotropy

KW - Quadrupole coupling

KW - RbVO

U2 - 10.1016/S0926-2040(99)00021-1

DO - 10.1016/S0926-2040(99)00021-1

M3 - Journal article

C2 - 10499666

AN - SCOPUS:0033181338

SN - 0926-2040

VL - 14

SP - 203

EP - 210

JO - Solid State Nuclear Magnetic Resonance

JF - Solid State Nuclear Magnetic Resonance

IS - 3-4