Slow magnetic relaxation in a two-dimensional dysprosium(III) coordination polymer

Shixiong She; Li Gong; Bo Wang; Yan Yang; Quan Lei; Beibei Liu; Gangping Su

doi:10.1016/j.inoche.2016.05.004

Slow magnetic relaxation in a two-dimensional dysprosium(III) coordination polymer

Shixiong She^*, Li Gong, Bo Wang, Yan Yang, Quan Lei, Beibei Liu, Gangping Su

^*Corresponding author for this work

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

6 Citations (Scopus)

Abstract

A new two-dimensional (2D) dysprosium(III) coordination polymer, e.g. [Dy(HL)(NO₃)₂(H₂O)]_n (1, H₂L = 4-{[(2-hydroxy-3-methoxyphenyl)methylidene]amino}benzoic acid)), has been solvothermally synthesized and structurally characterized using single-crystal X-ray diffraction. The dysprosium ions in complex 1 display the capped trigonal prism geometry and are connected with each other through o-vanillin and carboxyl groups, generating an interesting 2D structure with a Shubnikov topological symbol of {3²4.3.4} (tts). Magnetic investigations indicate that the coordination polymer exhibits slow magnetic relaxation.

Original language	English
Journal	Inorganic Chemistry Communications
Volume	70
Pages (from-to)	18-21
Number of pages	4
ISSN	1387-7003
DOIs	https://doi.org/10.1016/j.inoche.2016.05.004
Publication status	Published - 1 Aug 2016
Externally published	Yes

Keywords

Dysprosium
Slow magnetic relaxation
Two-dimensional coordination polymer

Access to Document

10.1016/j.inoche.2016.05.004

Cite this

@article{6068d632d8c74ba7a5c9079ea0fdd50a,

title = "Slow magnetic relaxation in a two-dimensional dysprosium(III) coordination polymer",

abstract = "A new two-dimensional (2D) dysprosium(III) coordination polymer, e.g. [Dy(HL)(NO3)2(H2O)]n (1, H2L = 4-{[(2-hydroxy-3-methoxyphenyl)methylidene]amino}benzoic acid)), has been solvothermally synthesized and structurally characterized using single-crystal X-ray diffraction. The dysprosium ions in complex 1 display the capped trigonal prism geometry and are connected with each other through o-vanillin and carboxyl groups, generating an interesting 2D structure with a Shubnikov topological symbol of {324.3.4} (tts). Magnetic investigations indicate that the coordination polymer exhibits slow magnetic relaxation.",

keywords = "Dysprosium, Slow magnetic relaxation, Two-dimensional coordination polymer",

author = "Shixiong She and Li Gong and Bo Wang and Yan Yang and Quan Lei and Beibei Liu and Gangping Su",

year = "2016",

month = aug,

day = "1",

doi = "10.1016/j.inoche.2016.05.004",

language = "English",

volume = "70",

pages = "18--21",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Slow magnetic relaxation in a two-dimensional dysprosium(III) coordination polymer

AU - She, Shixiong

AU - Gong, Li

AU - Wang, Bo

AU - Yang, Yan

AU - Lei, Quan

AU - Liu, Beibei

AU - Su, Gangping

PY - 2016/8/1

Y1 - 2016/8/1

N2 - A new two-dimensional (2D) dysprosium(III) coordination polymer, e.g. [Dy(HL)(NO3)2(H2O)]n (1, H2L = 4-{[(2-hydroxy-3-methoxyphenyl)methylidene]amino}benzoic acid)), has been solvothermally synthesized and structurally characterized using single-crystal X-ray diffraction. The dysprosium ions in complex 1 display the capped trigonal prism geometry and are connected with each other through o-vanillin and carboxyl groups, generating an interesting 2D structure with a Shubnikov topological symbol of {324.3.4} (tts). Magnetic investigations indicate that the coordination polymer exhibits slow magnetic relaxation.

AB - A new two-dimensional (2D) dysprosium(III) coordination polymer, e.g. [Dy(HL)(NO3)2(H2O)]n (1, H2L = 4-{[(2-hydroxy-3-methoxyphenyl)methylidene]amino}benzoic acid)), has been solvothermally synthesized and structurally characterized using single-crystal X-ray diffraction. The dysprosium ions in complex 1 display the capped trigonal prism geometry and are connected with each other through o-vanillin and carboxyl groups, generating an interesting 2D structure with a Shubnikov topological symbol of {324.3.4} (tts). Magnetic investigations indicate that the coordination polymer exhibits slow magnetic relaxation.

KW - Dysprosium

KW - Slow magnetic relaxation

KW - Two-dimensional coordination polymer

UR - http://www.scopus.com/inward/record.url?scp=84969752952&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2016.05.004

DO - 10.1016/j.inoche.2016.05.004

M3 - Journal article

AN - SCOPUS:84969752952

SN - 1387-7003

VL - 70

SP - 18

EP - 21

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Slow magnetic relaxation in a two-dimensional dysprosium(III) coordination polymer

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this