Selection of conformational states in surface self-assembly for a molecule with eight possible pairs of surface enantiomers

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaperJournal articleResearchpeer-review

Standard

Selection of conformational states in surface self-assembly for a molecule with eight possible pairs of surface enantiomers. / Nuermaimaiti, Ajiguli; Schultz-Falk, Vickie; Lind Cramer , Jacob ; Svane, Katrine Louise; Hammer, Bjørk; Gothelf, Kurt Vesterager; Linderoth, Trolle René.

In: Chemical Communications, Vol. 52, No. 97, 2016, p. 14023-14026.

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaperJournal articleResearchpeer-review

Harvard

APA

CBE

MLA

Vancouver

Author

Bibtex

@article{3fe24cfc48304c43a973fa0a894f8f0a,
title = "Selection of conformational states in surface self-assembly for a molecule with eight possible pairs of surface enantiomers",
abstract = "Self-assembly of a molecule with many distinct conformational states, resulting in eight possible pairs of surface enantiomers, is investigated on a Au(111) surface under UHV conditions. The complex molecule is equipped with alkyl and carboxyl moieties to promote controlled self-assembly of lamellae structures. From statistical analysis of Scanning Tunnelling Microscopy (STM) data we observe a clear selection of specific conformational states after self-assembly. Using Density Functional Theory (DFT) calculations we rationalise how this selection is correlated to the orientation of the alkyl moieties in mirror-image domains of the lamellae structures, leading to selection of three out of the eight possible enantiomeric pairs.",
author = "Ajiguli Nuermaimaiti and Vickie Schultz-Falk and {Lind Cramer}, Jacob and Svane, {Katrine Louise} and Bj{\o}rk Hammer and Gothelf, {Kurt Vesterager} and Linderoth, {Trolle Ren{\'e}}",
year = "2016",
doi = "10.1039/C6CC06876F",
language = "English",
volume = "52",
pages = "14023--14026",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "ROYAL SOC CHEMISTRY",
number = "97",

}

RIS

TY - JOUR

T1 - Selection of conformational states in surface self-assembly for a molecule with eight possible pairs of surface enantiomers

AU - Nuermaimaiti, Ajiguli

AU - Schultz-Falk, Vickie

AU - Lind Cramer , Jacob

AU - Svane, Katrine Louise

AU - Hammer, Bjørk

AU - Gothelf, Kurt Vesterager

AU - Linderoth, Trolle René

PY - 2016

Y1 - 2016

N2 - Self-assembly of a molecule with many distinct conformational states, resulting in eight possible pairs of surface enantiomers, is investigated on a Au(111) surface under UHV conditions. The complex molecule is equipped with alkyl and carboxyl moieties to promote controlled self-assembly of lamellae structures. From statistical analysis of Scanning Tunnelling Microscopy (STM) data we observe a clear selection of specific conformational states after self-assembly. Using Density Functional Theory (DFT) calculations we rationalise how this selection is correlated to the orientation of the alkyl moieties in mirror-image domains of the lamellae structures, leading to selection of three out of the eight possible enantiomeric pairs.

AB - Self-assembly of a molecule with many distinct conformational states, resulting in eight possible pairs of surface enantiomers, is investigated on a Au(111) surface under UHV conditions. The complex molecule is equipped with alkyl and carboxyl moieties to promote controlled self-assembly of lamellae structures. From statistical analysis of Scanning Tunnelling Microscopy (STM) data we observe a clear selection of specific conformational states after self-assembly. Using Density Functional Theory (DFT) calculations we rationalise how this selection is correlated to the orientation of the alkyl moieties in mirror-image domains of the lamellae structures, leading to selection of three out of the eight possible enantiomeric pairs.

U2 - 10.1039/C6CC06876F

DO - 10.1039/C6CC06876F

M3 - Journal article

VL - 52

SP - 14023

EP - 14026

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 97

ER -