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Relaxation dynamics in excited helium nanodroplets probed with high resolution, time-resolved photoelectron spectroscopy

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DOI

  • A. C. LaForge, University of Connecticut
  • ,
  • Jakob Dall Asmussen
  • Björn Bastian
  • ,
  • M. Bonanomi, Consiglio Nazionale delle Ricerche, Dipartimento di Fisica Politecnico
  • ,
  • C. Callegari, Sincrotrone Trieste
  • ,
  • S. De, Indian Institute of Technology, Madras
  • ,
  • Michele Di Fraia, Sincrotrone Trieste
  • ,
  • L. Gorman, University of Connecticut
  • ,
  • S. Hartweg, University of Freiburg
  • ,
  • S. R Krishnan, Indian Institute of Technology, Madras
  • ,
  • M. F. Kling, Ludwig Maximilian University of Munich, Max Planck Institute of Quantum Optics, Stanford Linear Accelerator Center, Stanford University
  • ,
  • D. Mishra, University of Connecticut
  • ,
  • S. Mandal, Indian Institute of Science Education and Research Pune, Denmark
  • Aaron Ngai, University of Freiburg
  • ,
  • N. Pal, Sincrotrone Trieste
  • ,
  • O. Plekan, Sincrotrone Trieste
  • ,
  • Kevin C Prince, Sincrotrone Trieste, Italy
  • P. Rosenberger, Ludwig Maximilian University of Munich, Max Planck Institute of Quantum Optics
  • ,
  • E. Aguirre Serrata, University of Connecticut
  • ,
  • F. Stienkemeier, University of Freiburg
  • ,
  • N. Berrah, University of Connecticut, United States
  • Marcel Mudrich

Superfluid helium nanodroplets are often considered as transparent and chemically inert nanometer-sized cryo-matrices for high-resolution or time-resolved spectroscopy of embedded molecules and clusters. On the other hand, when the helium nanodroplets are resonantly excited with XUV radiation, a multitude of ultrafast processes are initiated, such as relaxation into metastable states, formation of nanoscopic bubbles or excimers, and autoionization channels generating low-energy free electrons. Here, we discuss the full spectrum of ultrafast relaxation processes observed when helium nanodroplets are electronically excited. In particular, we perform an in-depth study of the relaxation dynamics occurring in the lowest 1s2s and 1s2p droplet bands using high resolution, time-resolved photoelectron spectroscopy. The simplified excitation scheme and improved resolution allow us to identify the relaxation into metastable triplet and excimer states even when exciting below the droplets' autoionization threshold, unobserved in previous studies.

Original languageEnglish
JournalPhysical Chemistry Chemical Physics
Volume24
Issue47
Pages (from-to)28844-28852
Number of pages9
ISSN1463-9076
DOIs
Publication statusPublished - Nov 2022

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