Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems

S. Ü Çelik; Ümit ̈ Akbey; Ayhan Bozkurt; Robert Graf; Hans W. Spiess

doi:10.1002/macp.200700457

Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems

S. Ü Çelik
, Ümit ̈ Akbey
, Ayhan Bozkurt^*
, Robert Graf
, Hans W. Spiess

^*Corresponding author for this work

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

48 Citations (Scopus)

Abstract

1,2,4-triazole-functional PGMA polymers have been synthesized and their anhydrous proton-conducting properties were investigated after doping with phosphoric acid and triflic acid. PGMA was prepared by solution polymerization and then modified with 1H-1,2,4-triazole (Tri) and 3-amino-1,2,4-triazole (ATri). FT-IR, ¹³C NMR and elemental analysis verify the high immobilization of the triazoles in the polymer chain. Phosphoric-acid-doped polymers showed lower T_g and higher proton conductivities. PGMA-Tri 4 H₃PO₄ showed a maximum water-free proton conductivity of approximately 10^-2 S · cm^-1 while that of PGMA-ATri 2 H₃PO₄ was 10^-3 S · cm^-1. The structure and dynamics of the polymers were explored by ¹H MAS and ¹³C CP-MAS solid-state NMR.

Original language	English
Journal	Macromolecular Chemistry and Physics
Volume	209
Issue	6
Pages (from-to)	593-603
Number of pages	11
ISSN	1022-1352
DOIs	https://doi.org/10.1002/macp.200700457
Publication status	Published - 25 Mar 2008

Keywords

1H-1,2,4-triazole
3-Amino-1,2,4-triazole
Anhydrous proton conductivity
Poly(glycidyl methacrylate)
Polymer electrolyte
Solid state NMR

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@article{11bafc98b61840458e283105b268eddf,

title = "Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems",

abstract = "1,2,4-triazole-functional PGMA polymers have been synthesized and their anhydrous proton-conducting properties were investigated after doping with phosphoric acid and triflic acid. PGMA was prepared by solution polymerization and then modified with 1H-1,2,4-triazole (Tri) and 3-amino-1,2,4-triazole (ATri). FT-IR, 13C NMR and elemental analysis verify the high immobilization of the triazoles in the polymer chain. Phosphoric-acid-doped polymers showed lower Tg and higher proton conductivities. PGMA-Tri 4 H3PO4 showed a maximum water-free proton conductivity of approximately 10-2 S · cm-1 while that of PGMA-ATri 2 H3PO4 was 10-3 S · cm-1. The structure and dynamics of the polymers were explored by 1H MAS and 13C CP-MAS solid-state NMR.",

keywords = "1H-1,2,4-triazole, 3-Amino-1,2,4-triazole, Anhydrous proton conductivity, Poly(glycidyl methacrylate), Polymer electrolyte, Solid state NMR",

author = "{\c C}elik, \{S. {\"U}\} and Akbey, \{{\"U}mit{\" }\} and Ayhan Bozkurt and Robert Graf and Spiess, \{Hans W.\}",

year = "2008",

month = mar,

day = "25",

doi = "10.1002/macp.200700457",

language = "English",

volume = "209",

pages = "593--603",

journal = "Macromolecular Chemistry and Physics",

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Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems. / Çelik, S. Ü; Akbey, Ümit ̈; Bozkurt, Ayhan et al.
In: Macromolecular Chemistry and Physics, Vol. 209, No. 6, 25.03.2008, p. 593-603.

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

TY - JOUR

T1 - Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems

AU - Çelik, S. Ü

AU - Akbey, Ümit ̈

AU - Bozkurt, Ayhan

AU - Graf, Robert

AU - Spiess, Hans W.

PY - 2008/3/25

Y1 - 2008/3/25

N2 - 1,2,4-triazole-functional PGMA polymers have been synthesized and their anhydrous proton-conducting properties were investigated after doping with phosphoric acid and triflic acid. PGMA was prepared by solution polymerization and then modified with 1H-1,2,4-triazole (Tri) and 3-amino-1,2,4-triazole (ATri). FT-IR, 13C NMR and elemental analysis verify the high immobilization of the triazoles in the polymer chain. Phosphoric-acid-doped polymers showed lower Tg and higher proton conductivities. PGMA-Tri 4 H3PO4 showed a maximum water-free proton conductivity of approximately 10-2 S · cm-1 while that of PGMA-ATri 2 H3PO4 was 10-3 S · cm-1. The structure and dynamics of the polymers were explored by 1H MAS and 13C CP-MAS solid-state NMR.

AB - 1,2,4-triazole-functional PGMA polymers have been synthesized and their anhydrous proton-conducting properties were investigated after doping with phosphoric acid and triflic acid. PGMA was prepared by solution polymerization and then modified with 1H-1,2,4-triazole (Tri) and 3-amino-1,2,4-triazole (ATri). FT-IR, 13C NMR and elemental analysis verify the high immobilization of the triazoles in the polymer chain. Phosphoric-acid-doped polymers showed lower Tg and higher proton conductivities. PGMA-Tri 4 H3PO4 showed a maximum water-free proton conductivity of approximately 10-2 S · cm-1 while that of PGMA-ATri 2 H3PO4 was 10-3 S · cm-1. The structure and dynamics of the polymers were explored by 1H MAS and 13C CP-MAS solid-state NMR.

KW - 1H-1,2,4-triazole

KW - 3-Amino-1,2,4-triazole

KW - Anhydrous proton conductivity

KW - Poly(glycidyl methacrylate)

KW - Polymer electrolyte

KW - Solid state NMR

U2 - 10.1002/macp.200700457

DO - 10.1002/macp.200700457

M3 - Journal article

AN - SCOPUS:54249122358

SN - 1022-1352

VL - 209

SP - 593

EP - 603

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 6

ER -

Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems

Abstract

Keywords

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