Photocatalytic Activity of Mesoporous Graphitic Carbon Nitride (mpg-C3N4) Towards Organic Chromophores Under UV and VIS Light Illumination

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  • Deniz Altunoz Erdogan, Bilkent University
  • ,
  • Melike Sevim, Ataturk University
  • ,
  • Ezgi Kısa, Koç University
  • ,
  • Dilara Borte Emiroglu, Bilkent University
  • ,
  • Mustafa Karatok, Bilkent University
  • ,
  • Evgeny I. Vovk, Boreskov Institute of Catalysis SB RAS
  • ,
  • Morten Bjerring
  • ,
  • Ümit Akbey
  • ,
  • Önder Metin, Ataturk University
  • ,
  • Emrah Ozensoy, Bilkent University

A template-assisted synthetic method including the thermal polycondensation of guanidine hydrochloride (GndCl) was utilized to synthesize highly-organized mesoporous graphitic carbon nitride (mpg-C3N4) photocatalysts. Comprehensive structural analysis of the mpg-C3N4 materials were performed by XPS, XRD, FT-IR, BET and solid-state NMR spectroscopy. Photocatalytic performance of the mpg-C3N4 materials was studied for the photodegradation of several dyes under visible and UV light illumination as a function of catalyst loading and the structure of mpg-C3N4 depending on the polycondensation temperature. Among all of the formerly reported performances in the literature (including the ones for Degussa P25 commercial benchmark), currently synthesized mpg-C3N4 photocatalysts exhibit a significantly superior visible light-induced photocatalytic activity towards rhodamine B (RhB) dye. Enhanced catalytic efficiency could be mainly attributed to the terminated polycondensation process, high specific surface area, and mesoporous structure with a wide pore size distribution.

Original languageEnglish
JournalTopics in Catalysis
Volume59
Issue15
Pages (from-to)1305-1318
Number of pages14
ISSN1022-5528
DOIs
Publication statusPublished - 2016

    Research areas

  • Carbon nitride, Graphitic-CN, Organic dyes, Photocatalytic degradation, UV–Vis light

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