Open frame-like Co-Fe oxides superstructures for highly efficient cross-dehydrogenative coupling reaction of N-phenyltetrahydroisoquinoline under mild conditions

Zhuo Xin; Jianyao Kou; Min Luo; Qing Liu; Mauro Carraro; Mingdong Dong; Kim Daasbjerg; Troels Skrydstrup; Yuxing Huang

doi:10.1016/j.inoche.2024.113352

Open frame-like Co-Fe oxides superstructures for highly efficient cross-dehydrogenative coupling reaction of N-phenyltetrahydroisoquinoline under mild conditions

Zhuo Xin, Jianyao Kou, Min Luo, Qing Liu, Mauro Carraro, Mingdong Dong, Kim Daasbjerg, Troels Skrydstrup, Yuxing Huang^*

^*Corresponding author for this work

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

Abstract

An open frame-like Co-Fe oxides catalyst has been successfully prepared using a time-controlled strategy. Benefiting from the unique open frame-like superstructure and synergistic bimetallic composition, this novel catalyst exhibits excellent catalytic activity (up to 91 % isolated yield) and substrate suitability for Cross-Dehydrogenative Coupling reaction (CDC) of N-phenyltetrahydroisoquinolines and nitroalkanes using oxygen as the oxidant under mild reaction conditions. And after several runs, the reused catalyst still maintains great stability. This may attributed to the interaction between Fe and Co. In addition, through the radical trapping experiments, we found that O₂^·− species play an important role in the cross-dehydrogenative coupling reaction.

Original language	English
Article number	113352
Journal	Inorganic Chemistry Communications
Volume	170
Issue	2
Number of pages	7
ISSN	1387-7003
DOIs	https://doi.org/10.1016/j.inoche.2024.113352
Publication status	Published - Dec 2024

Keywords

Co-Fe oxides
Cross-dehydrogenative coupling reaction
O species
Open frame-like superstructure

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10.1016/j.inoche.2024.113352

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Xin, Z., Kou, J., Luo, M., Liu, Q., Carraro, M., Dong, M., Daasbjerg, K., Skrydstrup, T., & Huang, Y. (2024). Open frame-like Co-Fe oxides superstructures for highly efficient cross-dehydrogenative coupling reaction of N-phenyltetrahydroisoquinoline under mild conditions. Inorganic Chemistry Communications, 170(2), Article 113352. https://doi.org/10.1016/j.inoche.2024.113352

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title = "Open frame-like Co-Fe oxides superstructures for highly efficient cross-dehydrogenative coupling reaction of N-phenyltetrahydroisoquinoline under mild conditions",

abstract = "An open frame-like Co-Fe oxides catalyst has been successfully prepared using a time-controlled strategy. Benefiting from the unique open frame-like superstructure and synergistic bimetallic composition, this novel catalyst exhibits excellent catalytic activity (up to 91 % isolated yield) and substrate suitability for Cross-Dehydrogenative Coupling reaction (CDC) of N-phenyltetrahydroisoquinolines and nitroalkanes using oxygen as the oxidant under mild reaction conditions. And after several runs, the reused catalyst still maintains great stability. This may attributed to the interaction between Fe and Co. In addition, through the radical trapping experiments, we found that O2·− species play an important role in the cross-dehydrogenative coupling reaction.",

keywords = "Co-Fe oxides, Cross-dehydrogenative coupling reaction, O species, Open frame-like superstructure",

author = "Zhuo Xin and Jianyao Kou and Min Luo and Qing Liu and Mauro Carraro and Mingdong Dong and Kim Daasbjerg and Troels Skrydstrup and Yuxing Huang",

note = "Publisher Copyright: {\textcopyright} 2024 Elsevier B.V.",

year = "2024",

month = dec,

doi = "10.1016/j.inoche.2024.113352",

language = "English",

volume = "170",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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Open frame-like Co-Fe oxides superstructures for highly efficient cross-dehydrogenative coupling reaction of N-phenyltetrahydroisoquinoline under mild conditions. / Xin, Zhuo; Kou, Jianyao; Luo, Min et al.
In: Inorganic Chemistry Communications, Vol. 170, No. 2, 113352, 12.2024.

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

TY - JOUR

T1 - Open frame-like Co-Fe oxides superstructures for highly efficient cross-dehydrogenative coupling reaction of N-phenyltetrahydroisoquinoline under mild conditions

AU - Xin, Zhuo

AU - Kou, Jianyao

AU - Luo, Min

AU - Liu, Qing

AU - Carraro, Mauro

AU - Dong, Mingdong

AU - Daasbjerg, Kim

AU - Skrydstrup, Troels

AU - Huang, Yuxing

PY - 2024/12

Y1 - 2024/12

N2 - An open frame-like Co-Fe oxides catalyst has been successfully prepared using a time-controlled strategy. Benefiting from the unique open frame-like superstructure and synergistic bimetallic composition, this novel catalyst exhibits excellent catalytic activity (up to 91 % isolated yield) and substrate suitability for Cross-Dehydrogenative Coupling reaction (CDC) of N-phenyltetrahydroisoquinolines and nitroalkanes using oxygen as the oxidant under mild reaction conditions. And after several runs, the reused catalyst still maintains great stability. This may attributed to the interaction between Fe and Co. In addition, through the radical trapping experiments, we found that O2·− species play an important role in the cross-dehydrogenative coupling reaction.

AB - An open frame-like Co-Fe oxides catalyst has been successfully prepared using a time-controlled strategy. Benefiting from the unique open frame-like superstructure and synergistic bimetallic composition, this novel catalyst exhibits excellent catalytic activity (up to 91 % isolated yield) and substrate suitability for Cross-Dehydrogenative Coupling reaction (CDC) of N-phenyltetrahydroisoquinolines and nitroalkanes using oxygen as the oxidant under mild reaction conditions. And after several runs, the reused catalyst still maintains great stability. This may attributed to the interaction between Fe and Co. In addition, through the radical trapping experiments, we found that O2·− species play an important role in the cross-dehydrogenative coupling reaction.

KW - Co-Fe oxides

KW - Cross-dehydrogenative coupling reaction

KW - O species

KW - Open frame-like superstructure

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U2 - 10.1016/j.inoche.2024.113352

DO - 10.1016/j.inoche.2024.113352

M3 - Journal article

AN - SCOPUS:85206976800

SN - 1387-7003

VL - 170

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 2

M1 - 113352

ER -

Open frame-like Co-Fe oxides superstructures for highly efficient cross-dehydrogenative coupling reaction of N-phenyltetrahydroisoquinoline under mild conditions

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