Oligo(naphthylene–ethynylene) Molecular Rods

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaperJournal articleResearchpeer-review

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Oligo(naphthylene–ethynylene) Molecular Rods. / Cramer, Jacob Roland; Ning, Yanxiao; Shen, Cai; Nuermaimaiti, Ajiguli; Besenbacher, Flemming; Linderoth, Trolle René; Gothelf, Kurt Vesterager.

In: European Journal of Organic Chemistry, Vol. 2013, No. 14, 05.2013, p. 2813-2822.

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaperJournal articleResearchpeer-review

Harvard

Cramer, JR, Ning, Y, Shen, C, Nuermaimaiti, A, Besenbacher, F, Linderoth, TR & Gothelf, KV 2013, 'Oligo(naphthylene–ethynylene) Molecular Rods', European Journal of Organic Chemistry, vol. 2013, no. 14, pp. 2813-2822. https://doi.org/10.1002/ejoc.201201752

APA

Cramer, J. R., Ning, Y., Shen, C., Nuermaimaiti, A., Besenbacher, F., Linderoth, T. R., & Gothelf, K. V. (2013). Oligo(naphthylene–ethynylene) Molecular Rods. European Journal of Organic Chemistry, 2013(14), 2813-2822. https://doi.org/10.1002/ejoc.201201752

CBE

Cramer JR, Ning Y, Shen C, Nuermaimaiti A, Besenbacher F, Linderoth TR, Gothelf KV. 2013. Oligo(naphthylene–ethynylene) Molecular Rods. European Journal of Organic Chemistry. 2013(14):2813-2822. https://doi.org/10.1002/ejoc.201201752

MLA

Cramer, Jacob Roland et al. "Oligo(naphthylene–ethynylene) Molecular Rods". European Journal of Organic Chemistry. 2013, 2013(14). 2813-2822. https://doi.org/10.1002/ejoc.201201752

Vancouver

Cramer JR, Ning Y, Shen C, Nuermaimaiti A, Besenbacher F, Linderoth TR et al. Oligo(naphthylene–ethynylene) Molecular Rods. European Journal of Organic Chemistry. 2013 May;2013(14):2813-2822. https://doi.org/10.1002/ejoc.201201752

Author

Cramer, Jacob Roland ; Ning, Yanxiao ; Shen, Cai ; Nuermaimaiti, Ajiguli ; Besenbacher, Flemming ; Linderoth, Trolle René ; Gothelf, Kurt Vesterager. / Oligo(naphthylene–ethynylene) Molecular Rods. In: European Journal of Organic Chemistry. 2013 ; Vol. 2013, No. 14. pp. 2813-2822.

Bibtex

@article{f63302f722ee44f88ebc51acf0c7f8b3,
title = "Oligo(naphthylene–ethynylene) Molecular Rods",
abstract = "Molecular rods designed for surface chirality studies have been synthesized in high yields. The molecules are composed of oligo(naphthylene–ethynylene) skeletons and functionalized at their two termini with carboxylic acids and hydrophobic groups. The molecular skeletons were constructed by means of palladium-catalyzed Sonogashira reactions between naphthyl halides and acetylenes. The triazene functionality was used as a protected iodine precursor to allow linear extension of the molecular rods during the synthe-ses. The carboxylic acid groups in the target molecules were protected as esters during the synthesis to keep the large aromatic molecules soluble during their syntheses. These rigidoligomers were designed to form lamella-like structures when adsorbed on a surface, through which multiple distinguishable surface conformations should be obtainable. Preliminary scanning tunneling microscopy imaging confirmedthese properties.",
keywords = "Self-assembly / Surface chirality / Surface analysis / Conformation analysis / Cross-coupling / Nanostructures",
author = "Cramer, {Jacob Roland} and Yanxiao Ning and Cai Shen and Ajiguli Nuermaimaiti and Flemming Besenbacher and Linderoth, {Trolle Ren{\'e}} and Gothelf, {Kurt Vesterager}",
year = "2013",
month = "5",
doi = "10.1002/ejoc.201201752",
language = "English",
volume = "2013",
pages = "2813--2822",
journal = "European Journal of Organic Chemistry",
issn = "1434-193X",
publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",
number = "14",

}

RIS

TY - JOUR

T1 - Oligo(naphthylene–ethynylene) Molecular Rods

AU - Cramer, Jacob Roland

AU - Ning, Yanxiao

AU - Shen, Cai

AU - Nuermaimaiti, Ajiguli

AU - Besenbacher, Flemming

AU - Linderoth, Trolle René

AU - Gothelf, Kurt Vesterager

PY - 2013/5

Y1 - 2013/5

N2 - Molecular rods designed for surface chirality studies have been synthesized in high yields. The molecules are composed of oligo(naphthylene–ethynylene) skeletons and functionalized at their two termini with carboxylic acids and hydrophobic groups. The molecular skeletons were constructed by means of palladium-catalyzed Sonogashira reactions between naphthyl halides and acetylenes. The triazene functionality was used as a protected iodine precursor to allow linear extension of the molecular rods during the synthe-ses. The carboxylic acid groups in the target molecules were protected as esters during the synthesis to keep the large aromatic molecules soluble during their syntheses. These rigidoligomers were designed to form lamella-like structures when adsorbed on a surface, through which multiple distinguishable surface conformations should be obtainable. Preliminary scanning tunneling microscopy imaging confirmedthese properties.

AB - Molecular rods designed for surface chirality studies have been synthesized in high yields. The molecules are composed of oligo(naphthylene–ethynylene) skeletons and functionalized at their two termini with carboxylic acids and hydrophobic groups. The molecular skeletons were constructed by means of palladium-catalyzed Sonogashira reactions between naphthyl halides and acetylenes. The triazene functionality was used as a protected iodine precursor to allow linear extension of the molecular rods during the synthe-ses. The carboxylic acid groups in the target molecules were protected as esters during the synthesis to keep the large aromatic molecules soluble during their syntheses. These rigidoligomers were designed to form lamella-like structures when adsorbed on a surface, through which multiple distinguishable surface conformations should be obtainable. Preliminary scanning tunneling microscopy imaging confirmedthese properties.

KW - Self-assembly / Surface chirality / Surface analysis / Conformation analysis / Cross-coupling / Nanostructures

U2 - 10.1002/ejoc.201201752

DO - 10.1002/ejoc.201201752

M3 - Journal article

VL - 2013

SP - 2813

EP - 2822

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 14

ER -