Nucleation and Aitken mode atmospheric particles in relation to O 3 and NO X at semirural background in Denmark

Jacob K. Nøjgaard*, Quynh T. Nguyen, Marianne Glasius, Lise L. Sørensen

*Corresponding author for this work

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaperJournal articleResearchpeer-review

4 Citations (Scopus)

Abstract

Atmospheric oxidants (O 3, NO and NO 2) and particle size distributions (6-700nm) were studied at a semi-rural background location in Denmark during 2009 to evaluate the sources of particulate matter. Aitken mode particles (30-110nm) and accumulation mode particles (110-700nm) anti-correlated or showed no correlation with O 3. The lower Aitken mode (<30nm), also referred to as the nucleation mode, typically peaked around noon from April to September and correlated positively with O 3, which indicates that photochemistry is likely to be responsible for most of the nucleation mode particles in this period of the year. In the months with low global radiation (October-March), NO 2 correlated positively with the lower Aitken mode, which typically peaked in the morning and afternoon on working days, indicating that traffic is the most important source of nucleation mode particles in that period of the year. A strong correlation was observed for NO 2 and Aitken mode particles throughout the year, which indicate a common traffic source. We also observed growth of Aitken mode particles during high NO X episodes. While photochemistry and traffic were major sources to Aitken mode particles, a source apportionment analysis identified Secondary Inorganic Aerosols (SIA), as the largest source to PM 10 (36% including secondary marine aerosols) in the semi-rural background troposphere in Denmark. Ammonium nitrate was a larger source than ammonium sulfate to the SIA mass fraction, where particulate nitrate exceeded that of sulfates by 2.6 times on a molar basis. Indications are that NO 2, as a precursor for e.g. ammonium nitrate is probably more important than SO 2, as a precursor for ammonium sulfate, in the formation of SIA. In this way, NO 2 from anthropogenic emissions and following conversion to particulate nitrates thus appeared to impact semi-rural atmospheric particulate matter in both the Aitken mode and mass wise in PM 10.

Original languageEnglish
JournalAtmospheric Environment
Volume49
Pages (from-to)275-283
Number of pages9
ISSN1352-2310
DOIs
Publication statusPublished - 1 Mar 2012

Keywords

  • Aitken mode
  • Atmospheric particles
  • Nucleation mode
  • Oxidants
  • Source apportionment

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