Locating Fe dopants in catalytic PtPd nanoparticles on γ-alumina using X-ray absorption spectroscopy

Espen Z. Eikeland; Hugo Silva; Lasse R. Jørgensen; Jonas Beyer; Toshiaki Ina; Henrik L. Hellstern; Christian Kallesøe; Leif H. Christensen; Bo B. Iversen

doi:10.1039/d0cy02307h

Locating Fe dopants in catalytic PtPd nanoparticles on γ-alumina using X-ray absorption spectroscopy

Espen Z. Eikeland, Hugo Silva, Lasse R. Jørgensen, Jonas Beyer, Toshiaki Ina, Henrik L. Hellstern, Christian Kallesøe, Leif H. Christensen, Bo B. Iversen^*

^*Corresponding author for this work

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

Abstract

Addition of Fe to PtPd nanoparticles on γ-alumina is known to increase catalytic activity. This is shown to stem from increased Pt-Pd coordination during thermal aging which induces microstrain. X-ray absorption spectroscopy analysis reveals that the Fe dopant atoms are incorporated into the alumina surface, which fine tunes the electronic state and provides greater oxidation resistance to Pt.

Original language	English
Journal	Catalysis Science and Technology
Volume	11
Issue	5
Pages (from-to)	1961-1964
Number of pages	4
ISSN	2044-4753
DOIs	https://doi.org/10.1039/d0cy02307h
Publication status	Published - Mar 2021

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10.1039/d0cy02307h

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title = "Locating Fe dopants in catalytic PtPd nanoparticles on γ-alumina using X-ray absorption spectroscopy",

abstract = "Addition of Fe to PtPd nanoparticles on γ-alumina is known to increase catalytic activity. This is shown to stem from increased Pt-Pd coordination during thermal aging which induces microstrain. X-ray absorption spectroscopy analysis reveals that the Fe dopant atoms are incorporated into the alumina surface, which fine tunes the electronic state and provides greater oxidation resistance to Pt.",

author = "Eikeland, {Espen Z.} and Hugo Silva and J{\o}rgensen, {Lasse R.} and Jonas Beyer and Toshiaki Ina and Hellstern, {Henrik L.} and Christian Kalles{\o}e and Christensen, {Leif H.} and Iversen, {Bo B.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = mar,

doi = "10.1039/d0cy02307h",

language = "English",

volume = "11",

pages = "1961--1964",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "ROYAL SOC CHEMISTRY",

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}

Locating Fe dopants in catalytic PtPd nanoparticles on γ-alumina using X-ray absorption spectroscopy. / Eikeland, Espen Z.; Silva, Hugo; Jørgensen, Lasse R. et al.
In: Catalysis Science and Technology, Vol. 11, No. 5, 03.2021, p. 1961-1964.

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

TY - JOUR

T1 - Locating Fe dopants in catalytic PtPd nanoparticles on γ-alumina using X-ray absorption spectroscopy

AU - Eikeland, Espen Z.

AU - Silva, Hugo

AU - Jørgensen, Lasse R.

AU - Beyer, Jonas

AU - Ina, Toshiaki

AU - Hellstern, Henrik L.

AU - Kallesøe, Christian

AU - Christensen, Leif H.

AU - Iversen, Bo B.

PY - 2021/3

Y1 - 2021/3

N2 - Addition of Fe to PtPd nanoparticles on γ-alumina is known to increase catalytic activity. This is shown to stem from increased Pt-Pd coordination during thermal aging which induces microstrain. X-ray absorption spectroscopy analysis reveals that the Fe dopant atoms are incorporated into the alumina surface, which fine tunes the electronic state and provides greater oxidation resistance to Pt.

AB - Addition of Fe to PtPd nanoparticles on γ-alumina is known to increase catalytic activity. This is shown to stem from increased Pt-Pd coordination during thermal aging which induces microstrain. X-ray absorption spectroscopy analysis reveals that the Fe dopant atoms are incorporated into the alumina surface, which fine tunes the electronic state and provides greater oxidation resistance to Pt.

UR - http://www.scopus.com/inward/record.url?scp=85103059115&partnerID=8YFLogxK

U2 - 10.1039/d0cy02307h

DO - 10.1039/d0cy02307h

M3 - Journal article

AN - SCOPUS:85103059115

SN - 2044-4753

VL - 11

SP - 1961

EP - 1964

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 5

ER -

Locating Fe dopants in catalytic PtPd nanoparticles on γ-alumina using X-ray absorption spectroscopy

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