Hydrogen sorption in TiZrNbHfTa high entropy alloy

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  • C. Zlotea, Université Paris-Est
  • ,
  • M. A. Sow, Université Paris-Est
  • ,
  • G. Ek, Uppsala University
  • ,
  • J-P Couzinie, Université Paris-Est
  • ,
  • L. Perriere, Université Paris-Est
  • ,
  • I. Guillot, Université Paris-Est
  • ,
  • J. Bourgon, Université Paris-Est
  • ,
  • K. T. Moller
  • ,
  • T. R. Jensen
  • E. Akiba, Kyushu University
  • ,
  • M. Sahlberg, Uppsala University

High Entropy Alloys (HEA), where five or more elements are mixed together in near equiatomic ratios offer promising properties as hydrogen storage materials due to their ability to crystallize in simple cubic structures in the presence of large lattice strain originating from the different sizes of the atoms. In this work, the hydrogen absorption and desorption as well as the cycling properties of the TiZrNbHfTa HEA have been studied by in situ Synchrotron X-Ray diffraction, Pressure-Composition-Isotherm, Thermal Desorption Spectroscopy and Differential Scanning Calorimetry. The alloy crystallizes in a cubic bcc phase and undergoes a two-stage hydrogen absorption reaction to a fcc dihydride phase with an intermediate tetragonal monohydride, very similar to the V-H system. The hydrogen absorption/desorption in TiZrNbHfTa is completely reversible and the activation energy of desorption could be calculated. Furthermore, we have observed an interesting macrostructure following parallel planes after the formation of the dihydride phase, which is retained after desorption.

Original languageEnglish
JournalJournal of Alloys and Compounds
Volume775
Pages (from-to)667-674
Number of pages8
ISSN0925-8388
DOIs
Publication statusPublished - Feb 2019

    Research areas

  • High entropy alloys, Hydrogen absorption/desorption, In situ synchrotron X-ray diffraction, Activation energy of hydrogen desorption, STORAGE PROPERTIES, DIFFRACTION, PHASE, MICROSTRUCTURE, ABSORPTION, MGH2

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