Highly stable silver nanoparticles for SERS applications

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  • S. M. Novikov, Syddansk Universitet, Moskovskij Fiziko-Tehniceskij Institut - Gosudarstvennyj Universitet
  • ,
  • V. N. Popok
  • ,
  • A. B. Evlyukhin, Syddansk Universitet, ITMO University
  • ,
  • M. Hanif
  • ,
  • P. Morgen, Syddansk Universitet
  • ,
  • J. Fiutowski, University of Southern Denmark, Sønderborg
  • ,
  • J. Beermann, Syddansk Universitet
  • ,
  • H. G. Rubahn, University of Southern Denmark, Sønderborg
  • ,
  • S. I. Bozhevolnyi, Syddansk Universitet

Plasmonics sensor configurations utilizing localized plasmon resonances in silver nanostructures typically suffer from rapid degradation of silver in ambient atmospheric conditions. In this work, we report on the fabrication and detailed characterization of ensembles of monocrystalline silver nanoparticles (NPs), which exhibit a long-term stability of optical properties under ambient conditions without any protective treatments. Ensembles with different densities (surface coverages) of size-selected NPs (diameters from 12.5 to 24 nm) on quartz substrates are fabricated using the cluster-beam technique and characterized by linear spectroscopy, surface-enhanced Raman scattering microscopy as well as transmission electron, helium-ion and atomic force microscopies. It is found that the fabricated ensembles of monocrystalline silver NPs preserve their plasmonic properties (monitored with optical spectroscopy) and strong field enhancements (revealed by surface enhanced Raman spectroscopy) at least 5 times longer as compared to chemically synthesized silver NPs with similar sizes. The obtained results are of high practical relevance for the further development of sensors, resonators and metamaterials utilizing plasmonic properties of silver NPs.

Original languageEnglish
Article number012098
Book seriesJournal of Physics: Conference Series
Volume1092
IssueConference 1
ISSN1742-6588
DOIs
Publication statusPublished - 1 Jan 2018
Event3rd International Conference on Metamaterials and Nanophotonics, METANANO 2018 - Sochi, Russian Federation
Duration: 17 Sep 201821 Sep 2018

Conference

Conference3rd International Conference on Metamaterials and Nanophotonics, METANANO 2018
CountryRussian Federation
CitySochi
Period17/09/201821/09/2018

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