Guanine- and Potassium-Based Two-Dimensional Coordination Network Self-Assembled on Au(111)

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  • iNano-School
  • Department of Physics and Astronomy
  • Interdisciplinary Nanoscience Center
In this study, through the choice of the well-known G-K biological coordination system, bioligand-alkali metal coordination has for the first time been brought onto an inert Au(111) surface. Using the interplay between high-resolution scanning tunneling microscopy and density functional theory calculations, we show that the mobile G molecules on Au(111) can effectively coordinate with the K atoms, resulting in a metallosupramolecular porous network that is stabilized by a delicate balance between hydrogen bonding and metal-organic coordination.
Original languageEnglish
JournalJournal of the American Chemical Society
Volume132
Issue45
Pages (from-to)15927-9
Number of pages3
ISSN0002-7863
DOIs
Publication statusPublished - 17 Nov 2010

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