Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust

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Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust. / Huang, Li-Zhi; Hansen, Hans Christian B.; Daasbjerg, Kim.

In: Journal of Hazardous Materials, Vol. 323, No. part B, 05.02.2017, p. 690-697.

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaperJournal articleResearchpeer-review

Harvard

Huang, L-Z, Hansen, HCB & Daasbjerg, K 2017, 'Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust', Journal of Hazardous Materials, vol. 323, no. part B, pp. 690-697. https://doi.org/10.1016/j.jhazmat.2016.10.038

APA

CBE

MLA

Huang, Li-Zhi, Hans Christian B. Hansen, and Kim Daasbjerg. "Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust". Journal of Hazardous Materials. 2017, 323(part B). 690-697. https://doi.org/10.1016/j.jhazmat.2016.10.038

Vancouver

Author

Huang, Li-Zhi ; Hansen, Hans Christian B. ; Daasbjerg, Kim. / Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust. In: Journal of Hazardous Materials. 2017 ; Vol. 323, No. part B. pp. 690-697.

Bibtex

@article{15a308f935604820a941f4279988cd51,
title = "Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust",
abstract = "Graphene-based nanomaterials can mediate environmentally relevant abiotic redox reactions of chlorinated aliphatic hydrocarbons. In this study as low amounts as similar to 0.007 % of graphene oxide (GO) was found to catalyze the reduction of carbon tetrachloride by layered Fe(II)-Fe(III) hydroxide (Green Rust, GR) in aqueous solutions with chloroform being the reduction product. On the basis of sorption studies of carbon tetrachloride onto the GO surface it is suggested that it is the amphiphilicity of GO, which initiates the reaction by providing a suitable reaction platform for the reagents. This study indicates that traces of graphene oxide can affect reaction pathways as well as kinetics for dechlorination processes in anoxic sediments by facilitating a partial dechlorination. (C) 2016 Elsevier B.V. All rights reserved.",
keywords = "Graphene oxide, Graphene, Green rust, Dechlorination mechanism, REDUCTIVE DECHLORINATION, WASTE-WATER, AQUEOUS-SOLUTIONS, NANOMATERIALS, SULFATE, NANOPARTICLES, TRANSFORMATION, NITROBENZENE, GROUNDWATER, ENVIRONMENT",
author = "Li-Zhi Huang and Hansen, {Hans Christian B.} and Kim Daasbjerg",
year = "2017",
month = feb,
day = "5",
doi = "10.1016/j.jhazmat.2016.10.038",
language = "English",
volume = "323",
pages = "690--697",
journal = "Journal of Hazardous Materials",
issn = "0304-3894",
publisher = "Elsevier BV",
number = "part B",

}

RIS

TY - JOUR

T1 - Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust

AU - Huang, Li-Zhi

AU - Hansen, Hans Christian B.

AU - Daasbjerg, Kim

PY - 2017/2/5

Y1 - 2017/2/5

N2 - Graphene-based nanomaterials can mediate environmentally relevant abiotic redox reactions of chlorinated aliphatic hydrocarbons. In this study as low amounts as similar to 0.007 % of graphene oxide (GO) was found to catalyze the reduction of carbon tetrachloride by layered Fe(II)-Fe(III) hydroxide (Green Rust, GR) in aqueous solutions with chloroform being the reduction product. On the basis of sorption studies of carbon tetrachloride onto the GO surface it is suggested that it is the amphiphilicity of GO, which initiates the reaction by providing a suitable reaction platform for the reagents. This study indicates that traces of graphene oxide can affect reaction pathways as well as kinetics for dechlorination processes in anoxic sediments by facilitating a partial dechlorination. (C) 2016 Elsevier B.V. All rights reserved.

AB - Graphene-based nanomaterials can mediate environmentally relevant abiotic redox reactions of chlorinated aliphatic hydrocarbons. In this study as low amounts as similar to 0.007 % of graphene oxide (GO) was found to catalyze the reduction of carbon tetrachloride by layered Fe(II)-Fe(III) hydroxide (Green Rust, GR) in aqueous solutions with chloroform being the reduction product. On the basis of sorption studies of carbon tetrachloride onto the GO surface it is suggested that it is the amphiphilicity of GO, which initiates the reaction by providing a suitable reaction platform for the reagents. This study indicates that traces of graphene oxide can affect reaction pathways as well as kinetics for dechlorination processes in anoxic sediments by facilitating a partial dechlorination. (C) 2016 Elsevier B.V. All rights reserved.

KW - Graphene oxide

KW - Graphene

KW - Green rust

KW - Dechlorination mechanism

KW - REDUCTIVE DECHLORINATION

KW - WASTE-WATER

KW - AQUEOUS-SOLUTIONS

KW - NANOMATERIALS

KW - SULFATE

KW - NANOPARTICLES

KW - TRANSFORMATION

KW - NITROBENZENE

KW - GROUNDWATER

KW - ENVIRONMENT

U2 - 10.1016/j.jhazmat.2016.10.038

DO - 10.1016/j.jhazmat.2016.10.038

M3 - Journal article

C2 - 27776856

VL - 323

SP - 690

EP - 697

JO - Journal of Hazardous Materials

JF - Journal of Hazardous Materials

SN - 0304-3894

IS - part B

ER -