Direct on-surface synthesis of gold-phthalocyanine: Via cyclization of cyano-groups with gold adatoms

Zhongping Wang; Xiaoqing Liu; Yan Lu; Zegao Wang; Christian Bortolini; Menglin Chen; Sheng Wei; Wei Li; Junfa Zhu; Huanxin Ju; Federico Rosei; Mingdong Dong; Li Wang

doi:10.1039/c9qm00070d

Direct on-surface synthesis of gold-phthalocyanine: Via cyclization of cyano-groups with gold adatoms

Zhongping Wang, Xiaoqing Liu, Yan Lu, Zegao Wang, Christian Bortolini, Menglin Chen, Sheng Wei, Wei Li, Junfa Zhu, Huanxin Ju, Federico Rosei, Mingdong Dong^*, Li Wang

^*Corresponding author for this work

Interdisciplinary Nanoscience Center - INANO-Fysik, iNANO-huset

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

5 Citations (Scopus)

Abstract

We report the synthesis of gold-phthalocyanines on an Au(111) surface via cyclization of dibenzo[fg,op]tetracene-5,6,12,13-tetracarbonitrile molecules. Scanning tunnelling microscopic images unambiguously reveal that gold adatoms act as linkers via metal coordination bonding to form metastable supra-molecular structures, and simultaneously replace metal ions within the final products, metal phthalocyanines.

Original language	English
Journal	Materials Chemistry Frontiers
Volume	3
Issue	7
Pages (from-to)	1406-1410
Number of pages	5
DOIs	https://doi.org/10.1039/c9qm00070d
Publication status	Published - 1 Jul 2019

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10.1039/c9qm00070d

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title = "Direct on-surface synthesis of gold-phthalocyanine: Via cyclization of cyano-groups with gold adatoms",

abstract = "We report the synthesis of gold-phthalocyanines on an Au(111) surface via cyclization of dibenzo[fg,op]tetracene-5,6,12,13-tetracarbonitrile molecules. Scanning tunnelling microscopic images unambiguously reveal that gold adatoms act as linkers via metal coordination bonding to form metastable supra-molecular structures, and simultaneously replace metal ions within the final products, metal phthalocyanines.",

author = "Zhongping Wang and Xiaoqing Liu and Yan Lu and Zegao Wang and Christian Bortolini and Menglin Chen and Sheng Wei and Wei Li and Junfa Zhu and Huanxin Ju and Federico Rosei and Mingdong Dong and Li Wang",

year = "2019",

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doi = "10.1039/c9qm00070d",

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Direct on-surface synthesis of gold-phthalocyanine: Via cyclization of cyano-groups with gold adatoms. / Wang, Zhongping; Liu, Xiaoqing; Lu, Yan et al.
In: Materials Chemistry Frontiers, Vol. 3, No. 7, 01.07.2019, p. 1406-1410.

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review

TY - JOUR

T1 - Direct on-surface synthesis of gold-phthalocyanine

T2 - Via cyclization of cyano-groups with gold adatoms

AU - Wang, Zhongping

AU - Liu, Xiaoqing

AU - Lu, Yan

AU - Wang, Zegao

AU - Bortolini, Christian

AU - Chen, Menglin

AU - Wei, Sheng

AU - Li, Wei

AU - Zhu, Junfa

AU - Ju, Huanxin

AU - Rosei, Federico

AU - Dong, Mingdong

AU - Wang, Li

PY - 2019/7/1

Y1 - 2019/7/1

N2 - We report the synthesis of gold-phthalocyanines on an Au(111) surface via cyclization of dibenzo[fg,op]tetracene-5,6,12,13-tetracarbonitrile molecules. Scanning tunnelling microscopic images unambiguously reveal that gold adatoms act as linkers via metal coordination bonding to form metastable supra-molecular structures, and simultaneously replace metal ions within the final products, metal phthalocyanines.

AB - We report the synthesis of gold-phthalocyanines on an Au(111) surface via cyclization of dibenzo[fg,op]tetracene-5,6,12,13-tetracarbonitrile molecules. Scanning tunnelling microscopic images unambiguously reveal that gold adatoms act as linkers via metal coordination bonding to form metastable supra-molecular structures, and simultaneously replace metal ions within the final products, metal phthalocyanines.

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U2 - 10.1039/c9qm00070d

DO - 10.1039/c9qm00070d

M3 - Journal article

AN - SCOPUS:85068179785

SN - 2052-1537

VL - 3

SP - 1406

EP - 1410

JO - Materials Chemistry Frontiers

JF - Materials Chemistry Frontiers

IS - 7

ER -

Direct on-surface synthesis of gold-phthalocyanine: Via cyclization of cyano-groups with gold adatoms

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