Coulomb-explosion imaging of concurrent CH2 BrI photodissociation dynamics
Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaper › Journal article › Research › peer-review
Links
- https://arxiv.org/pdf/1710.02372.pdf
Accepted manuscript
DOI
- https://doi.org/10.1103/PhysRevA.96.043415
Final published version
- Michael Burt, University of Oxford, Oxford ,
- Rebecca Boll, DESY Photon Science ,
- Jason W.L. Lee, University of Oxford, Oxford ,
- Kasra Amini, University of Oxford, Oxford ,
- Hansjochen Köckert, University of Oxford, Oxford ,
- Claire Vallance, University of Oxford, Oxford ,
- Alexander S. Gentleman, University of Oxford, Oxford ,
- Stuart R. Mackenzie, University of Oxford, Oxford ,
- Sadia Bari, DESY Photon Science ,
- Cédric Bomme, DESY Photon Science ,
- Stefan Düsterer, DESY Photon Science ,
- Benjamin Erk, DESY Photon Science ,
- Bastian Manschwetus, DESY Photon Science ,
- Erland Müller, DESY Photon Science ,
- Dimitrios Rompotis, DESY Photon Science ,
- Evgeny Savelyev, DESY Photon Science ,
- Nora Schirmel, DESY Photon Science ,
- Simone Techert, DESY Photon Science, Max Planck Institute for Biophysical Chemistry (Karl Friedrich Bonhoeffer Institute), University of Göttingen ,
- Rolf Treusch, DESY Photon Science ,
- Jochen Küpper, DESY Photon Science, Universitat Hamburg ,
- Sebastian Trippel, DESY Photon Science, Universitat Hamburg ,
- Joss Wiese, DESY Photon Science ,
- Henrik Stapelfeldt
- Barbara Cunha De Miranda, LOCEAN Laboratory ,
- Renaud Guillemin, LOCEAN Laboratory ,
- Iyas Ismail, LOCEAN Laboratory ,
- Loïc Journel, LOCEAN Laboratory ,
- Tatiana Marchenko, LOCEAN Laboratory ,
- Jérôme Palaudoux, LOCEAN Laboratory ,
- Francis Penent, LOCEAN Laboratory ,
- Maria Novella Piancastelli, LOCEAN Laboratory, Uppsala University ,
- Marc Simon, LOCEAN Laboratory ,
- Oksana Travnikova, LOCEAN Laboratory ,
- Felix Brausse, Max Born Institute, 12489 Berlin ,
- Gildas Goldsztejn, Max Born Institute, 12489 Berlin ,
- Arnaud Rouzée, Max Born Institute, 12489 Berlin ,
- Marie Géléoc, Universite Paris-Saclay ,
- Romain Geneaux, Universite Paris-Saclay ,
- Thierry Ruchon, Universite Paris-Saclay ,
- Jonathan Underwood, UCL ,
- David M.P. Holland, Daresbury Laboratory ,
- Andrey S. Mereshchenko, Saint Petersburg State University ,
- Pavel K. Olshin, Saint Petersburg State University ,
- Per Johnsson, Lunds Universitet ,
- Sylvain Maclot, Lunds Universitet ,
- Jan Lahl, Lunds Universitet ,
- Artem Rudenko, Kansas State University ,
- Farzaneh Ziaee, Kansas State University ,
- Mark Brouard, University of Oxford, Oxford ,
- Daniel Rolles, Kansas State University
The dynamics following laser-induced molecular photodissociation of gas-phase CH2BrI at 271.6 nm were investigated by time-resolved Coulomb-explosion imaging using intense near-IR femtosecond laser pulses. The observed delay-dependent photofragment momenta reveal that CH2BrI undergoes C-I cleavage, depositing 65.6% of the available energy into internal product states, and that absorption of a second UV photon breaks the C-Br bond of CH2Br. Simulations confirm that this mechanism is consistent with previous data recorded at 248 nm, demonstrating the sensitivity of Coulomb-explosion imaging as a real-time probe of chemical dynamics.
| Original language | English |
|---|---|
| Article number | 043415 |
| Journal | Physical Review A |
| Volume | 96 |
| Issue | 4 |
| ISSN | 2469-9926 |
| DOIs | |
| Publication status | Published - 17 Oct 2017 |
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