Controlled Release of Reactive Gases: A Tale of Taming Carbon Monoxide

Anne K. Ravn, Martin B. Johansen, Troels Skrydstrup*

*Corresponding author for this work

Research output: Contribution to journal/Conference contribution in journal/Contribution to newspaperReviewResearchpeer-review

Abstract

This Personal Account describes the development of air-stable and solid precursors for on-demand release of carbon monoxide. In combination with the development of a two-chamber reactor, COware®, CO liberation can be achieved under safe working conditions, as well as allowing transition metal-mediated carbonylations with stoichiometric carbon monoxide. Particularly appealing is the adaptability of this chemical technology for the preparation of carbon isotope labeled bioactive compounds.

Original languageEnglish
JournalChemPlusChem
Volume85
Issue7
Pages (from-to)1529-1533
Number of pages5
ISSN2192-6506
DOIs
Publication statusPublished - Jul 2020

Keywords

  • carbon monoxide
  • carbonylation
  • catalysis
  • isotope labeling
  • reactors
  • COMPLEXES
  • EX-SITU GENERATION
  • TMSCF3
  • FLUORIDE
  • ARYL BROMIDES
  • IODIDES
  • OXIDATIVE-ADDITION
  • DERIVATIVES

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