Carbonylative Heck Reactions Using CO Generated ex Situ in a Two-Chamber System

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A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of the hazardous CO gas is obtained affording chalcone derivatives in good yields. Application to isotope labeling, incorporating 13CO, was further established.

Original languageEnglish
JournalOrganic Letters
Volume13
Issue9
Pages (from-to)2444-2447
ISSN1523-7060
DOIs
Publication statusPublished - 2011

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