Adsorption and dehydrogenation of tetrahydroxybenzene on Cu(111)

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Adsorption of tetrahydroxybenzene (THB) on Cu(111) and Au(111) surfaces is studied using a combination of STM, XPS, and DFT. THB is deposited intact, but on Cu(111) it undergoes gradual dehydrogenation of the hydroxyl groups as a function of substrate temperature, yielding a pure dihydroxy-benzoquinone phase at 370 K. Subtle changes to the adsorption structure upon dehydrogenation are explained from differences in molecule–surface bonding.
Original languageEnglish
JournalChemical Communications
Volume49
Issue81
Pages (from-to)9308-9310
Number of pages3
ISSN1359-7345
DOIs
Publication statusPublished - 18 Oct 2013

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