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Accurate values for the 27Al chemical shielding anisotropy (CSA) are reported for sapphire (α-Al2O3). The values (δσ = -17.3 ± 0.6 ppm, ησ = 0.03 ± 0.06) are obtained from single-crystal 27Al NMR and appear to be the first convincing determination of an 27Al CSA.
Original language | English |
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Journal | Journal of Magnetic Resonance |
Volume | 128 |
Issue | 2 |
Pages (from-to) | 135-137 |
Number of pages | 3 |
ISSN | 1090-7807 |
DOIs | |
Publication status | Published - 1997 |
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ID: 85936991