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27Al Chemical Shielding Anisotropy

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Accurate values for the 27Al chemical shielding anisotropy (CSA) are reported for sapphire (α-Al2O3). The values (δσ = -17.3 ± 0.6 ppm, ησ = 0.03 ± 0.06) are obtained from single-crystal 27Al NMR and appear to be the first convincing determination of an 27Al CSA.

Original languageEnglish
JournalJournal of Magnetic Resonance
Pages (from-to)135-137
Number of pages3
Publication statusPublished - 1997

    Research areas

  • α-AlO, Al chemical shielding anisotropy, Al quadrupole coupling, Sapphire, Single-crystal Al NMR

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ID: 85936991