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Alyssa Jean Lehsau Findlay

Trace metal concentration and partitioning in the first 1.5m of hydrothermal vent plumes along the Mid-Atlantic Ridge: TAG, Snakepit, and Rainbow

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  • Alyssa J. Findlay
  • Amy Gartman, University of Delaware, United States Geological Survey
  • ,
  • Timothy J. Shaw, University of South Carolina
  • ,
  • George W. Luther, University of Delaware

To determine the significance of metal fluxes from hydrothermal vents, understanding the speciation, reactivity, and possible transformations of metals and metal sulfides within the hydrothermal plume is critical. In this study, we measure the concentration and partitioning of trace metals (Fe, Mn, Cu, Cd, Co, Pb, Ni) and sulfide phases within the first 1.5m of the rising plume at three vent fields (TAG, Snakepit, and Rainbow) along the Mid-Atlantic Ridge. A HCl/HNO3 leaching method was used to differentiate metals present in metal mono-sulfides from those in pyrite and chalcopyrite. At all three vent sites, Mn and Fe are primarily in the <0.2μm (filtered) portion, whereas Cu, Co, Cd, and Pb are mainly in the unfiltered fraction. Significant concentrations of HNO3-extractable metals were found in the <0.2μm fraction at all three vent sites, indicating that they likely exist in a recalcitrant nanoparticulate phase such as pyrite or chalcopyrite. At TAG and Snakepit, Cu is correlated with Co, as Co enters into chalcopyrite and other CuFeS phases and Zn is correlated with Cd and Pb as they form discrete metal sulfide phases. At Rainbow, Zn, Cd, and Pb are correlated, but Cu and Co are not correlated. The Rainbow data are consistent with the higher metal to sulfide ratio found at Rainbow. These speciation differences are significant as both mineral type and size will affect the amount of metal transported from the vent site and its availability for biogeochemical processes.

Original languageEnglish
JournalChemical Geology
Volume412
Pages (from-to)117-131
Number of pages15
ISSN0009-2541
DOIs
Publication statusPublished - 7 Sep 2015
Externally publishedYes

    Research areas

  • Hydrothermal vent, Metal sulfide, Mid-Atlantic Ridge, Nanoparticles, Trace metals

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