The interconversion between THF•B3H7 and B3H8-: an efficient synthetic method for MB3H8 (M = Li and Na)

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  • Xin-Ran Liu, Henan Normal University
  • ,
  • Xi-Meng Chen, Henan Normal University
  • ,
  • Jie Zhang, Henan Normal University
  • ,
  • Torben R. Jensen
  • Xuenian Chen, Henan Normal University, Zhengzhou University

An efficient synthetic method for MB3H8 (M = Li and Na) has been developed with improved yields on the basis of the investigation of the interconversion between THFB3H7 and corresponding MB3H8. The mechanism was tentatively proposed based on the understanding of the nucleophilicity of the B-H bonding pair electrons.

OriginalsprogEngelsk
TidsskriftDalton Transactions
Vol/bind48
Nummer16
Sider (fra-til)5140-5143
Antal sider4
ISSN1477-9226
DOI
StatusUdgivet - apr. 2019

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