Synthesis of nortropane alkaloid calystegine B2 from methyl α-D-xylopyranoside

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A new synthetic route for formation of a central cycloheptanone intermediate leading to the nortropane alkaloid calystegine B2 is described. The approach installs the desired ketone functionality directly in a ring-closing metathesis step. The target compound was prepared over 10 steps from commercially available methyl α-D-xylopyranoside.

OriginalsprogEngelsk
TidsskriftCarbohydrate Research
Vol/bind472
Sider (fra-til)122-126
Antal sider5
ISSN0008-6215
DOI
StatusUdgivet - 15 jan. 2019

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