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Synthesis of homochiral tris-indanyl molecular rods

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Homochiral tris-indanyl molecular rods designed for supramolecular surface self-assembly were synthesized. The chiral indanol moiety was constructed via a Ti-mediated alkyne trimerization. Further manipulations resulted in a homochiral indanol monomer. This was employed as the precursor for successive Sonogashira and Ohira-Bestman reactions towards the homochiral tris-indanyl molecular rods. The molecular rods will be applied for scanning tunnelling microscopy studies of their surface self-assembly and chirality.
OriginalsprogEngelsk
TidsskriftOrganic & Biomolecular Chemistry
Vol/bind12
Nummer22
Sider (fra-til)3679-3685
Antal sider7
ISSN1477-0520
DOI
StatusUdgivet - 28 mar. 2014

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