SYNTHESIS AND HYDROLYSIS OF NEW ASPIRIN-DERIVED AND TRIFLUSAL-DERIVED ORTHO ESTERS AND ANHYDRIDES

L FALBORG, A SENNING

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Abstract

Ten new 2-substituted 2-methyl-2-oxy-4H-1,3-benzodioxin-4-ones, 4a-i and 6, have been synthesized and their rate constants of pseudo-first-order non-enzymatic hydrolysis determined. One of the compounds, 2-(2-acetoxybenzoyloxy)-2-methyl-4H-1,3-benzodioxin-4-one, 6, is a new anhydride of aspirin. The analogous triflusal derivative, 10, has also been synthesized.

OriginalsprogEngelsk
TidsskriftDalton Transactions (Print Edition)
Vol/bind47
Nummer5
Sider (fra-til)514-520
Antal sider7
ISSN0904-213X
StatusUdgivet - maj 1993

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