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Sensitivity of the glass transition and melting in a metal–organic framework to ligand chemistry

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The effect of substituting linkers with electron-donating moieties for part of the conventional ones on the melting and glass transition behaviours of ZIF-62 was investigated by calorimetry and X-ray diffraction. Specifically, substituting 5,6-dimethylbenzimidazole for benzimidazole in ZIF-62 increases both Tm and Tg. The structural origin of this effect was explained.

OriginalsprogEngelsk
TidsskriftChemical Communications
Vol/bind58
Nummer6
Sider (fra-til)823-826
Antal sider4
ISSN1359-7345
DOI
StatusUdgivet - jan. 2022

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