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Sensitivity of the glass transition and melting in a metal–organic framework to ligand chemistry
Publikation: Bidrag til tidsskrift/Konferencebidrag i tidsskrift /Bidrag til avis › Tidsskriftartikel › Forskning › peer review
DOI
- https://doi.org/10.1039/d1cc03541j
Forlagets udgivne version
- Rasmus S.K. Madsen, Aalborg Universitet ,
- Sounak Sarkar ,
- Bo Brummerstedt Iversen
- Yuanzheng Yue, Aalborg Universitet
The effect of substituting linkers with electron-donating moieties for part of the conventional ones on the melting and glass transition behaviours of ZIF-62 was investigated by calorimetry and X-ray diffraction. Specifically, substituting 5,6-dimethylbenzimidazole for benzimidazole in ZIF-62 increases both Tm and Tg. The structural origin of this effect was explained.
| Originalsprog | Engelsk |
|---|---|
| Tidsskrift | Chemical Communications |
| Vol/bind | 58 |
| Nummer | 6 |
| Sider (fra-til) | 823-826 |
| Antal sider | 4 |
| ISSN | 1359-7345 |
| DOI | |
| Status | Udgivet - jan. 2022 |
Bibliografisk note
Publisher Copyright:
This journal is © The Royal Society of Chemistry
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ID: 231462278