Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems

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Standard

Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems. / Çelik, S. Ü; Akbey, Ümit ̈; Bozkurt, Ayhan; Graf, Robert; Spiess, Hans W.

I: Macromolecular Chemistry and Physics, Bind 209, Nr. 6, 25.03.2008, s. 593-603.

Publikation: Bidrag til tidsskrift/Konferencebidrag i tidsskrift /Bidrag til avisTidsskriftartikelForskningpeer review

Harvard

Çelik, SÜ, Akbey, Ü, Bozkurt, A, Graf, R & Spiess, HW 2008, 'Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems', Macromolecular Chemistry and Physics, bind 209, nr. 6, s. 593-603. https://doi.org/10.1002/macp.200700457

APA

Çelik, S. Ü., Akbey, Ü. ., Bozkurt, A., Graf, R., & Spiess, H. W. (2008). Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems. Macromolecular Chemistry and Physics, 209(6), 593-603. https://doi.org/10.1002/macp.200700457

CBE

Çelik SÜ, Akbey Ü, Bozkurt A, Graf R, Spiess HW. 2008. Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems. Macromolecular Chemistry and Physics. 209(6):593-603. https://doi.org/10.1002/macp.200700457

MLA

Vancouver

Çelik SÜ, Akbey Ü, Bozkurt A, Graf R, Spiess HW. Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems. Macromolecular Chemistry and Physics. 2008 mar 25;209(6):593-603. https://doi.org/10.1002/macp.200700457

Author

Çelik, S. Ü ; Akbey, Ümit ̈ ; Bozkurt, Ayhan ; Graf, Robert ; Spiess, Hans W. / Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems. I: Macromolecular Chemistry and Physics. 2008 ; Bind 209, Nr. 6. s. 593-603.

Bibtex

@article{11bafc98b61840458e283105b268eddf,
title = "Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems",
abstract = "1,2,4-triazole-functional PGMA polymers have been synthesized and their anhydrous proton-conducting properties were investigated after doping with phosphoric acid and triflic acid. PGMA was prepared by solution polymerization and then modified with 1H-1,2,4-triazole (Tri) and 3-amino-1,2,4-triazole (ATri). FT-IR, 13C NMR and elemental analysis verify the high immobilization of the triazoles in the polymer chain. Phosphoric-acid-doped polymers showed lower Tg and higher proton conductivities. PGMA-Tri 4 H3PO4 showed a maximum water-free proton conductivity of approximately 10-2 S · cm-1 while that of PGMA-ATri 2 H3PO4 was 10-3 S · cm-1. The structure and dynamics of the polymers were explored by 1H MAS and 13C CP-MAS solid-state NMR.",
keywords = "1H-1,2,4-triazole, 3-Amino-1,2,4-triazole, Anhydrous proton conductivity, Poly(glycidyl methacrylate), Polymer electrolyte, Solid state NMR",
author = "{\cC}elik, {S. {\"U}} and Akbey, {{\"U}mit ̈} and Ayhan Bozkurt and Robert Graf and Spiess, {Hans W.}",
year = "2008",
month = "3",
day = "25",
doi = "10.1002/macp.200700457",
language = "English",
volume = "209",
pages = "593--603",
journal = "Macromolecular Chemistry and Physics",
issn = "1022-1352",
publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",
number = "6",

}

RIS

TY - JOUR

T1 - Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems

AU - Çelik, S. Ü

AU - Akbey, Ümit ̈

AU - Bozkurt, Ayhan

AU - Graf, Robert

AU - Spiess, Hans W.

PY - 2008/3/25

Y1 - 2008/3/25

N2 - 1,2,4-triazole-functional PGMA polymers have been synthesized and their anhydrous proton-conducting properties were investigated after doping with phosphoric acid and triflic acid. PGMA was prepared by solution polymerization and then modified with 1H-1,2,4-triazole (Tri) and 3-amino-1,2,4-triazole (ATri). FT-IR, 13C NMR and elemental analysis verify the high immobilization of the triazoles in the polymer chain. Phosphoric-acid-doped polymers showed lower Tg and higher proton conductivities. PGMA-Tri 4 H3PO4 showed a maximum water-free proton conductivity of approximately 10-2 S · cm-1 while that of PGMA-ATri 2 H3PO4 was 10-3 S · cm-1. The structure and dynamics of the polymers were explored by 1H MAS and 13C CP-MAS solid-state NMR.

AB - 1,2,4-triazole-functional PGMA polymers have been synthesized and their anhydrous proton-conducting properties were investigated after doping with phosphoric acid and triflic acid. PGMA was prepared by solution polymerization and then modified with 1H-1,2,4-triazole (Tri) and 3-amino-1,2,4-triazole (ATri). FT-IR, 13C NMR and elemental analysis verify the high immobilization of the triazoles in the polymer chain. Phosphoric-acid-doped polymers showed lower Tg and higher proton conductivities. PGMA-Tri 4 H3PO4 showed a maximum water-free proton conductivity of approximately 10-2 S · cm-1 while that of PGMA-ATri 2 H3PO4 was 10-3 S · cm-1. The structure and dynamics of the polymers were explored by 1H MAS and 13C CP-MAS solid-state NMR.

KW - 1H-1,2,4-triazole

KW - 3-Amino-1,2,4-triazole

KW - Anhydrous proton conductivity

KW - Poly(glycidyl methacrylate)

KW - Polymer electrolyte

KW - Solid state NMR

U2 - 10.1002/macp.200700457

DO - 10.1002/macp.200700457

M3 - Journal article

AN - SCOPUS:54249122358

VL - 209

SP - 593

EP - 603

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

SN - 1022-1352

IS - 6

ER -