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Organocatalytic Formation of Chiral Trisubstituted Allenes and Chiral Furan Derivatives
Publikation: Bidrag til tidsskrift/Konferencebidrag i tidsskrift /Bidrag til avis › Tidsskriftartikel › Forskning › peer review
DOI
- https://doi.org/10.1002/anie.201806238
Forlagets udgivne version
- Pernille H. Poulsen ,
- Yang Li ,
- Vibeke H. Lauridsen
- Danny K.B. Jørgensen ,
- Teresa A. Palazzo ,
- Marta Meazza ,
- Karl Anker Jørgensen
A novel reaction that provides chiral allenes by amino catalytic activation of either aldehydes or α,β-unsaturated aldehydes for reaction with alkynyl-substituted enones is presented. The reaction forms a variety of trisubstituted allenes in high yields and with excellent stereoselectivities. The utility of the reaction concept is demonstrated by the synthesis of chiral furan derivatives in high yields and stereoselectivities.
| Originalsprog | Engelsk |
|---|---|
| Tidsskrift | Angewandte Chemie - International Edition |
| Vol/bind | 57 |
| Nummer | 33 |
| Sider (fra-til) | 10661-10665 |
| Antal sider | 5 |
| ISSN | 1433-7851 |
| DOI | |
| Status | Udgivet - 13 aug. 2018 |
Se relationer på Aarhus Universitet Citationsformater
ID: 131908669