Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrode

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Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrode. / Abbasi, Amir Reza; Yousefshahi, Mohammadreza; Daasbjerg, Kim.

I: Journal of Inorganic and Organometallic Polymers and Materials, Bind 30, Nr. 6, 2020, s. 2027-2038.

Publikation: Bidrag til tidsskrift/Konferencebidrag i tidsskrift /Bidrag til avisTidsskriftartikelForskningpeer review

Harvard

Abbasi, AR, Yousefshahi, M & Daasbjerg, K 2020, 'Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrode', Journal of Inorganic and Organometallic Polymers and Materials, bind 30, nr. 6, s. 2027-2038. https://doi.org/10.1007/s10904-020-01452-6

APA

CBE

MLA

Abbasi, Amir Reza, Mohammadreza Yousefshahi, og Kim Daasbjerg. "Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrode". Journal of Inorganic and Organometallic Polymers and Materials. 2020, 30(6). 2027-2038. https://doi.org/10.1007/s10904-020-01452-6

Vancouver

Author

Abbasi, Amir Reza ; Yousefshahi, Mohammadreza ; Daasbjerg, Kim. / Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrode. I: Journal of Inorganic and Organometallic Polymers and Materials. 2020 ; Bind 30, Nr. 6. s. 2027-2038.

Bibtex

@article{f6af73f249df4e39b0bddc32c2446f15,
title = "Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrode",
abstract = "Herein, we introduce a simple set of experiments to construct non-enzymatic glucose sensors. The modification procedure was initiated by electrodeposition of nickel-coordination polymers (denoted henceforth as Ni-CPs) at the surface of glassy carbon (GC) electrode decorated with carbonnanotubes (CNTs). The electrochemical sensing of glucose occurred through the electrocatalytic oxidation of glucose by the Ni-CP using the CNTs as a high-area catalyst support. During potential cycling, the continuous chemical regeneration of the Ni(II) in the reaction between Ni(III) and glucose expresses itself as a dramatic enhancement of the anodic current pertaining to the Ni(III)/Ni(II) redox couple. Effects of various factors such as scan rate and solution pH were evaluated. For the optimized sensor the detection limit was as low as 2.1 μM glucose and with a linear response extending up to 400 μM. The modified electrode showed good reproducibility, excellent anti-interference performance, and high stability during the electrochemical experiments. Moreover, the analytical function of the non-enzymatic sensors for quantitative detection of glucose was assessed in real samples with satisfying results.",
keywords = "Carbon nanotubes, Coordination polymers, Electrocatalytic oxidation, Glucose",
author = "Abbasi, {Amir Reza} and Mohammadreza Yousefshahi and Kim Daasbjerg",
year = "2020",
doi = "10.1007/s10904-020-01452-6",
language = "English",
volume = "30",
pages = "2027--2038",
journal = "Journal of Inorganic and Organometallic Polymers and Materials",
issn = "1574-1443",
publisher = "Springer New York LLC",
number = "6",

}

RIS

TY - JOUR

T1 - Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrode

AU - Abbasi, Amir Reza

AU - Yousefshahi, Mohammadreza

AU - Daasbjerg, Kim

PY - 2020

Y1 - 2020

N2 - Herein, we introduce a simple set of experiments to construct non-enzymatic glucose sensors. The modification procedure was initiated by electrodeposition of nickel-coordination polymers (denoted henceforth as Ni-CPs) at the surface of glassy carbon (GC) electrode decorated with carbonnanotubes (CNTs). The electrochemical sensing of glucose occurred through the electrocatalytic oxidation of glucose by the Ni-CP using the CNTs as a high-area catalyst support. During potential cycling, the continuous chemical regeneration of the Ni(II) in the reaction between Ni(III) and glucose expresses itself as a dramatic enhancement of the anodic current pertaining to the Ni(III)/Ni(II) redox couple. Effects of various factors such as scan rate and solution pH were evaluated. For the optimized sensor the detection limit was as low as 2.1 μM glucose and with a linear response extending up to 400 μM. The modified electrode showed good reproducibility, excellent anti-interference performance, and high stability during the electrochemical experiments. Moreover, the analytical function of the non-enzymatic sensors for quantitative detection of glucose was assessed in real samples with satisfying results.

AB - Herein, we introduce a simple set of experiments to construct non-enzymatic glucose sensors. The modification procedure was initiated by electrodeposition of nickel-coordination polymers (denoted henceforth as Ni-CPs) at the surface of glassy carbon (GC) electrode decorated with carbonnanotubes (CNTs). The electrochemical sensing of glucose occurred through the electrocatalytic oxidation of glucose by the Ni-CP using the CNTs as a high-area catalyst support. During potential cycling, the continuous chemical regeneration of the Ni(II) in the reaction between Ni(III) and glucose expresses itself as a dramatic enhancement of the anodic current pertaining to the Ni(III)/Ni(II) redox couple. Effects of various factors such as scan rate and solution pH were evaluated. For the optimized sensor the detection limit was as low as 2.1 μM glucose and with a linear response extending up to 400 μM. The modified electrode showed good reproducibility, excellent anti-interference performance, and high stability during the electrochemical experiments. Moreover, the analytical function of the non-enzymatic sensors for quantitative detection of glucose was assessed in real samples with satisfying results.

KW - Carbon nanotubes

KW - Coordination polymers

KW - Electrocatalytic oxidation

KW - Glucose

UR - http://www.scopus.com/inward/record.url?scp=85080859243&partnerID=8YFLogxK

U2 - 10.1007/s10904-020-01452-6

DO - 10.1007/s10904-020-01452-6

M3 - Journal article

AN - SCOPUS:85080859243

VL - 30

SP - 2027

EP - 2038

JO - Journal of Inorganic and Organometallic Polymers and Materials

JF - Journal of Inorganic and Organometallic Polymers and Materials

SN - 1574-1443

IS - 6

ER -