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Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8

Publikation: Bidrag til tidsskrift/Konferencebidrag i tidsskrift /Bidrag til avis › Tidsskriftartikel › Forskning › peer review

Standard

Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8. / Ovchinnikov, Alexander; Mudring, Anja Verena.
I: Inorganic Chemistry, Bind 61, Nr. 25, 06.2022, s. 9756-9766.

Publikation: Bidrag til tidsskrift/Konferencebidrag i tidsskrift /Bidrag til avis › Tidsskriftartikel › Forskning › peer review

Harvard

Ovchinnikov, A & Mudring, AV 2022, 'Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8', Inorganic Chemistry, bind 61, nr. 25, s. 9756-9766. https://doi.org/10.1021/acs.inorgchem.2c01248

APA

Ovchinnikov, A., & Mudring, A. V. (2022). Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8. Inorganic Chemistry, 61(25), 9756-9766. https://doi.org/10.1021/acs.inorgchem.2c01248

CBE

Ovchinnikov A, Mudring AV. 2022. Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8. Inorganic Chemistry. 61(25):9756-9766. https://doi.org/10.1021/acs.inorgchem.2c01248

MLA

Ovchinnikov, Alexander og Anja Verena Mudring. "Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8". Inorganic Chemistry. 2022, 61(25). 9756-9766. https://doi.org/10.1021/acs.inorgchem.2c01248

Vancouver

Ovchinnikov A, Mudring AV. Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8. Inorganic Chemistry. 2022 jun.;61(25):9756-9766. doi: 10.1021/acs.inorgchem.2c01248

Author

Ovchinnikov, Alexander ; Mudring, Anja Verena. / Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8. I: Inorganic Chemistry. 2022 ; Bind 61, Nr. 25. s. 9756-9766.

Bibtex

@article{031150764cde419cbea0d7ac16888188,
title = "Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8",
abstract = "Reaction of the elements yielded Ca3Pt4Bi8 and CaPtBi, which are, to the best of our knowledge, the first reported ternary Ca-Pt-Bi compounds. The compounds crystallize isostructural to the Pd analogs Ca3Pd4Bi8 (own structure type) and CaPdBi (TiNiSi structure type), respectively. Employing a multistep temperature treatment allows for the growth of mm-sized single crystals of Ca3Pd4Bi8 and Ca3Pt4Bi8 from a Bi self-flux. Their crystal structures can be visualized as consisting of a threedimensional extended polyanion [M4Bi8]6- (M = Pd, Pt), composed of interlinked M-Bi chains propagating along the c direction, and Ca2+ cations residing in one-dimensional channels between the chains. First-principles calculations reveal quasi-onedimensional electronic behavior with reduced effective electron masses along [001]. Bader analysis points to a strong anionic character of the M species (M = Pd, Pt) in Ca3M4Bi8. Thus, it is more appropriate to address the compounds Ca3Pd4Bi8 and Ca3Pt4Bi8 as a palladide and platinide, respectively. Magnetization measurements indicate diamagnetic behavior with no indications for superconductivity down to 2 K. Electrical resistivity data are consistent with metallic behavior and suggest predominant electron-phonon scattering.",
author = "Alexander Ovchinnikov and Mudring, {Anja Verena}",
note = "Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",
year = "2022",
month = jun,
doi = "10.1021/acs.inorgchem.2c01248",
language = "English",
volume = "61",
pages = "9756--9766",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "AMER CHEMICAL SOC",
number = "25",

}

RIS

TY - JOUR

T1 - Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8

AU - Ovchinnikov, Alexander

AU - Mudring, Anja Verena

N1 - Publisher Copyright: © 2022 American Chemical Society.

PY - 2022/6

Y1 - 2022/6

N2 - Reaction of the elements yielded Ca3Pt4Bi8 and CaPtBi, which are, to the best of our knowledge, the first reported ternary Ca-Pt-Bi compounds. The compounds crystallize isostructural to the Pd analogs Ca3Pd4Bi8 (own structure type) and CaPdBi (TiNiSi structure type), respectively. Employing a multistep temperature treatment allows for the growth of mm-sized single crystals of Ca3Pd4Bi8 and Ca3Pt4Bi8 from a Bi self-flux. Their crystal structures can be visualized as consisting of a threedimensional extended polyanion [M4Bi8]6- (M = Pd, Pt), composed of interlinked M-Bi chains propagating along the c direction, and Ca2+ cations residing in one-dimensional channels between the chains. First-principles calculations reveal quasi-onedimensional electronic behavior with reduced effective electron masses along [001]. Bader analysis points to a strong anionic character of the M species (M = Pd, Pt) in Ca3M4Bi8. Thus, it is more appropriate to address the compounds Ca3Pd4Bi8 and Ca3Pt4Bi8 as a palladide and platinide, respectively. Magnetization measurements indicate diamagnetic behavior with no indications for superconductivity down to 2 K. Electrical resistivity data are consistent with metallic behavior and suggest predominant electron-phonon scattering.

AB - Reaction of the elements yielded Ca3Pt4Bi8 and CaPtBi, which are, to the best of our knowledge, the first reported ternary Ca-Pt-Bi compounds. The compounds crystallize isostructural to the Pd analogs Ca3Pd4Bi8 (own structure type) and CaPdBi (TiNiSi structure type), respectively. Employing a multistep temperature treatment allows for the growth of mm-sized single crystals of Ca3Pd4Bi8 and Ca3Pt4Bi8 from a Bi self-flux. Their crystal structures can be visualized as consisting of a threedimensional extended polyanion [M4Bi8]6- (M = Pd, Pt), composed of interlinked M-Bi chains propagating along the c direction, and Ca2+ cations residing in one-dimensional channels between the chains. First-principles calculations reveal quasi-onedimensional electronic behavior with reduced effective electron masses along [001]. Bader analysis points to a strong anionic character of the M species (M = Pd, Pt) in Ca3M4Bi8. Thus, it is more appropriate to address the compounds Ca3Pd4Bi8 and Ca3Pt4Bi8 as a palladide and platinide, respectively. Magnetization measurements indicate diamagnetic behavior with no indications for superconductivity down to 2 K. Electrical resistivity data are consistent with metallic behavior and suggest predominant electron-phonon scattering.

UR - http://www.scopus.com/inward/record.url?scp=85133102665&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.2c01248

DO - 10.1021/acs.inorgchem.2c01248

M3 - Journal article

C2 - 35704846

AN - SCOPUS:85133102665

VL - 61

SP - 9756

EP - 9766

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 25

ER -