Abstract
Monophasic undoped and cerium-doped Sr 4 Al 14 O 25 samples with partial substitution of calcium for strontium were prepared using conventional solid-state synthesis. Structural studies revealed that substitution of strontium by calcium in Sr 4-x Ca x Al 14 O 25 up to x = 1.4 is possible without formation of additional phases and that the Sr2 site (of two possible) is more likely to be substituted by the smaller Ca ions. Photoluminescence measurements of Sr 4 Al 14 O 25 :Ce showed emission with double peak (360 and 380 nm) under 330 nm excitation wavelength. The effect of partial substitution of strontium by calcium on the luminescence of Sr 4-x Ca x Al 14 O 25 :Ce (emission, quantum yield, decay) were studied as well.
Originalsprog | Engelsk |
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Tidsskrift | Journal of Solid State Chemistry |
Vol/bind | 274 |
Nummer | June |
Sider (fra-til) | 116-123 |
Antal sider | 8 |
ISSN | 0022-4596 |
DOI | |
Status | Udgivet - 2019 |