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An Atomistic Model Describing the Structure and Morphology of Cu-Doped C-S-H Hardening Accelerator Nanoparticles

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  • Gregorio Dal Sasso, CNR
  • ,
  • Maria Chiara Dalconi, University of Padova
  • ,
  • Giorgio Ferrari, Mapei S.p.A.
  • ,
  • Jan Skov Pedersen
  • Sergio Tamburini, CNR
  • ,
  • Federica Bertolotti, University of Insubria
  • ,
  • Antonietta Guagliardi, CNR
  • ,
  • Marco Bruno, University of Turin
  • ,
  • Luca Valentini, University of Padova
  • ,
  • Gilberto Artioli, University of Padova

Calcium silicate hydrate (C-S-H) is the main binding phase in Portland cement. The addition of C-S-H nanoparticles as nucleation seeds has successfully been used to accelerate the hydration process and the precipitation of binding phases either in conventional Portland cement or in alternative binders. Indeed, the modulation of the hydration kinetics during the early-stage dissolution-precipitation reactions, by acting on the nucleation and growth of binding phases, improves the early strength development. The fine-tuning of concrete properties in terms of compressive strength and durability by designed structural modifications can be achieved through the detailed description of the reaction products at the atomic scale. The nano-sized, chemically complex and structurally disordered nature of these phases hamper their thorough structural characterization. To this aim, we implement a novel multi-scale approach by combining forefront small-angle X-ray scattering (SAXS) and synchrotron wide-angle X-ray total scattering (WAXTS) analyses for the characterization of Cu-doped C-S-H nanoparticles dispersed in a colloidal suspension, used as hardening accelerator. SAXS and WAXTS data were analyzed under a unified modeling approach by developing suitable atomistic models for C-S-H nanoparticles to be used to simulate the experimental X-ray scattering pattern through the Debye scattering equation. The optimization of atomistic models against the experimental pattern, together with complementary information on the structural local order from29Si solid-state nuclear magnetic resonance and X-ray absorption spectroscopy, provided a comprehensive description of the structure, size and morphology of C-S-H nanoparticles from the atomic to the nanometer scale. C-S-H nanoparticles were modeled as an assembly of layers composed of 7-fold coordinated Ca atoms and decorated by silicate dimers and chains. The structural layers are a few tens of nanometers in length and width, with a crystal structure resembling that of a defective tobermorite, but lacking any ordering between stacking layers.

Antal sider21
StatusUdgivet - 21 jan. 2022

Bibliografisk note

Funding Information:
This work was financially supported by Mapei.S.p.A. through the research agreement between Mapei S.p.A. and Università degli Studi di Padova. Acknowledgments: The scientific and technical staff at the X04SA-MS beamline of the Swiss Light Source (Paul Scherrer Institut, Villigen, CH) and at the XAFS beamline of the Elettra Synchrotron light source (IT) is heartily acknowledged. We thank Norberto Masciocchi for the fruitful discussion.

Publisher Copyright:
© 2022 by the authors. Licensee MDPI, Basel, Switzerland.

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