Aarhus University Seal / Aarhus Universitets segl

Trolle René Linderoth

Guanine- and Potassium-Based Two-Dimensional Coordination Network Self-Assembled on Au(111)

Publikation: Bidrag til tidsskrift/Konferencebidrag i tidsskrift /Bidrag til avisTidsskriftartikelForskningpeer review

  • Interdisciplinær Nanoscience Forskerskole
  • Institut for Fysik og Astronomi
  • Interdisciplinary Nanoscience Center
In this study, through the choice of the well-known G-K biological coordination system, bioligand-alkali metal coordination has for the first time been brought onto an inert Au(111) surface. Using the interplay between high-resolution scanning tunneling microscopy and density functional theory calculations, we show that the mobile G molecules on Au(111) can effectively coordinate with the K atoms, resulting in a metallosupramolecular porous network that is stabilized by a delicate balance between hydrogen bonding and metal-organic coordination.
OriginalsprogEngelsk
TidsskriftJournal of the American Chemical Society
Vol/bind132
Nummer45
Sider (fra-til)15927-9
Antal sider3
ISSN0002-7863
DOI
StatusUdgivet - 17 nov. 2010

Se relationer på Aarhus Universitet Citationsformater

ID: 34277002