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Marcel Mudrich

Homo- and heteronuclear alkali metal trimers formed on helium nanodroplets. Part II. Femtosecond spectroscopy and spectra assignments

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DOI

  • Christian Giese, Physikalisches Institut, Albert-Ludwigs-Universität Freiburg
  • ,
  • Frank Stienkemeier, Albert-Ludwigs-Universität Freiburg
  • ,
  • Marcel Mudrich
  • Andreas W. Hauser, Massey University
  • ,
  • Wolfgang E. Ernst, Graz University of Technology

Homo- and heteronuclear alkali quartet trimers of type K 3-nRbn (n = 0,1,2,3) formed on helium nanodroplets are probed by one-color femtosecond (fs) photoionization (PI) spectroscopy. The obtained frequencies are assigned to vibrations in different electronic states in comparison to high level ab initio calculations of the involved potentials including pronounced Jahn-Teller and spin-orbit couplings. Despite the fact that the resulting complex vibronic structure of the heavy alkali molecules complicates the comparison of experiment and theory we find good agreement for many of the observed lines for all species.

OriginalsprogEngelsk
TidsskriftPhysical Chemistry Chemical Physics
Vol/bind13
Nummer42
Sider (fra-til)18769-18780
Antal sider12
ISSN1463-9076
DOI
StatusUdgivet - 14 nov. 2011
Eksternt udgivetJa

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