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Henning Lund

Photoinduced 1,2,3,4-tetrahydropyridine ring conversions

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DOI

  • Baiba Turovska, Department of Physical Organic Chemistry, Latvian Institute of Organic Synthesis, Aizkraukles 21, Riga , Letland
  • Henning Lund
  • Viesturs Lusis, Department of Physical Organic Chemistry, Latvian Institute of Organic Synthesis, Aizkraukles 21, Riga , Letland
  • Anna Lielpetere, Department of Physical Organic Chemistry, Latvian Institute of Organic Synthesis, Aizkraukles 21, Riga , Letland
  • Edvards Liepins, Department of Physical Organic Chemistry, Latvian Institute of Organic Synthesis, Aizkraukles 21, Riga , Letland
  • Sergejs Beljakovs, Department of Physical Organic Chemistry, Latvian Institute of Organic Synthesis, Aizkraukles 21, Riga , Letland
  • Inguna Goba, Department of Physical Organic Chemistry, Latvian Institute of Organic Synthesis, Aizkraukles 21, Riga , Letland
  • Janis Stradins, Department of Physical Organic Chemistry, Latvian Institute of Organic Synthesis, Aizkraukles 21, Riga , Letland

Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by O-3(2) if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome of the reaction depends on the light intensity and the concentration of O-2. In the solid state the heterocyclic hydroperoxide is stable; in solution it is involved in further reactions.

OriginalsprogEngelsk
TidsskriftBeilstein Journal of Organic Chemistry
Vol/bind11
Sider (fra-til)2166-2170
Antal sider5
ISSN2195-951X
DOI
StatusUdgivet - 2015

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