Structural evolution and stability of Sc2(WO4)3 after discharge in a sodium-based electrochemical cell

Research output: Research - peer-reviewJournal article

DOI

  • Henrik L Andersen
  • Othman K Al Bahri
    Othman K Al BahriSchool of Chemistry, UNSW Australia, Sydney NSW 2052, Australia. Neeraj.sharma@unsw.edu.au.
  • Sergey Tsarev
    Sergey TsarevSkolkovo Institute of Science and Technology Nobel St. 3, Moscow 143026, Russia.
  • Bernt Johannessen
    Bernt JohannessenAustralian Synchrotron, Clayton, Victoria 3168, Australia.
  • Bernd Schulz
    Bernd SchulzSchool of Chemistry, UNSW Australia, Sydney NSW 2052, Australia. Neeraj.sharma@unsw.edu.au.
  • Junnan Liu
    Junnan LiuSchool of Chemistry, UNSW Australia, Sydney NSW 2052, Australia. Neeraj.sharma@unsw.edu.au.
  • Helen E A Brand
    Helen E A BrandAustralian Synchrotron, Clayton, Victoria 3168, Australia.
  • Mogens Christensen
  • Neeraj Sharma
    Neeraj SharmaSchool of Chemistry, UNSW Australia, Sydney NSW 2052, Australia. Neeraj.sharma@unsw.edu.au.

Sc2(WO4)3, prepared by solid state synthesis and constructed as an electrode, is discharged to different states in half-cell batteries, versus a Na negative electrode. The structural evolution of the Na-containing electrodes is studied with synchrotron powder X-ray diffraction (PXRD) revealing an increase in microstrain and a gradual amorphization taking place with increasing Na content in the electrode. This indicates that a conversion reaction takes place in the electrochemical cell. X-ray absorption spectroscopy (XAS) at the tungsten L3 absorption edge shows a reduction in the tungsten oxidation state. Variable temperature (VT) PXRD shows that the Sc2(WO4)3 electrode remains relatively stable at higher temperatures, while the Na-containing samples undergo a number of phase transitions and/or turn amorphous above ∼400 °C. Although, Sc2(WO4)3 is a negative thermal expansion (NTE) material only a subtle change of the thermal expansion is found below 400 °C for the Na-containing electrodes. This work shows the complexity in employing an electrochemical cell to produce Na-containing Sc2(WO4)3 and the subsequent phase transitions.

Original languageEnglish
JournalDalton Transactions (Print Edition)
Volume47
Issue number4
Pages (from-to)1251-1260
Number of pages10
ISSN1477-9226
DOIs
StatePublished - Jan 2018

    Research areas

  • Journal Article

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